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The strain energy in the form of elastic deformation is mostly recoverable in the form of mechanical work. For example, the heat of combustion of cyclopropane (696 kJ/mol) is higher than that of propane (657 kJ/mol) for each additional CH 2 unit. Compounds with unusually large strain energy include tetrahedranes, propellanes, cubane-type ...
The J-integral represents a way to calculate the strain energy release rate, or work per unit fracture surface area, in a material. [1] The theoretical concept of J-integral was developed in 1967 by G. P. Cherepanov [2] and independently in 1968 by James R. Rice, [3] who showed that an energetic contour path integral (called J) was independent of the path around a crack.
There are situations where seemingly identical conformations are not equal in strain energy. Syn-pentane strain is an example of this situation. There are two different ways to put both of the bonds the central in n-pentane into a gauche conformation, one of which is 3 kcal mol −1 higher in energy than the other. [1]
A strain energy density function or stored energy density function is a scalar-valued function that relates the strain energy density of a material to the deformation ...
Plot of Load vs. Displacement. The energy release rate is defined [3] as the instantaneous loss of total potential energy per unit crack growth area , , where the total potential energy is written in terms of the total strain energy , surface traction , displacement , and body force by
Castigliano's method for calculating displacements is an application of his second theorem, which states: If the strain energy of a linearly elastic structure can be expressed as a function of generalised force Q i then the partial derivative of the strain energy with respect to generalised force gives the generalised displacement q i in the direction of Q i.
For rubber and biological materials, more sophisticated models are necessary. Such materials may exhibit a non-linear stress–strain behaviour at modest strains, or are elastic up to huge strains. These complex non-linear stress–strain behaviours need to be accommodated by specifically tailored strain-energy density functions.
In continuum mechanics, a Mooney–Rivlin solid [1] [2] is a hyperelastic material model where the strain energy density function is a linear combination of two invariants of the left Cauchy–Green deformation tensor.