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For example, laundry on a clothes line will dry (by evaporation) more rapidly on a windy day than on a still day. Three key parts to evaporation are heat, atmospheric pressure (determines the percent humidity), and air movement. On a molecular level, there is no strict boundary between the liquid state and the vapor state.
Evaporation is a phase transition from the liquid phase to vapor (a state of substance below critical temperature) that occurs at temperatures below the boiling temperature at a given pressure. Evaporation occurs on the surface. Evaporation only occurs when the partial pressure of vapor of a substance is less than the equilibrium vapor pressure ...
The basic form of a 2-dimensional thin film equation is [3] [4] [5] = where the fluid flux is = [(+ ^) + ^] +, and μ is the viscosity (or dynamic viscosity) of the liquid, h(x,y,t) is film thickness, γ is the interfacial tension between the liquid and the gas phase above it, is the liquid density and the surface shear.
The Penman equation describes evaporation (E) from an open water surface, and was developed by Howard Penman in 1948. Penman's equation requires daily mean temperature, wind speed, air pressure, and solar radiation to predict E. Simpler Hydrometeorological equations continue to be used where obtaining such data is impractical, to give comparable results within specific contexts, e.g. humid vs ...
The Kelvin equation describes the change in vapour pressure due to a curved liquid–vapor interface, such as the surface of a droplet. The vapor pressure at a convex curved surface is higher than that at a flat surface. The Kelvin equation is dependent upon thermodynamic principles and does not allude to special properties of materials.
The Hertz–Knudsen equation describes the non-dissociative adsorption of a gas molecule on a surface by expressing the variation of the number of molecules impacting on the surfaces per unit of time as a function of the pressure of the gas and other parameters which characterise both the gas phase molecule and the surface: [1] [2]
Temperature-dependency of the heats of vaporization for water, methanol, benzene, and acetone. In thermodynamics, the enthalpy of vaporization (symbol ∆H vap), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy that must be added to a liquid substance to transform a quantity of that substance into a gas.
The Antoine equation [3] [4] is a pragmatic mathematical expression of the relation between the vapor pressure and the temperature of pure liquid or solid substances. It is obtained by curve-fitting and is adapted to the fact that vapor pressure is usually increasing and concave as a function of temperature. The basic form of the equation is: