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Hume-Rothery rules, named after William Hume-Rothery, are a set of basic rules that describe the conditions under which an element could dissolve in a metal, forming a solid solution. There are two sets of rules; one refers to substitutional solid solutions, and the other refers to interstitial solid solutions.
The nearly-free electron debacle compelled researchers to modify the assumpition that ions flowed in a sea of free electrons. A number of quantum mechanical models were developed, such as band structure calculations based on molecular orbitals, and the density functional theory. These models either depart from the atomic orbitals of neutral ...
A forming limit diagram, also known as a forming limit curve, is used in sheet metal forming for predicting forming behavior of sheet metal. [1] [2] The diagram attempts to provide a graphical description of material failure tests, such as a punched dome test. In order to determine whether a given region has failed, a mechanical test is performed.
Main-group element, an element other than a transition metal; Ligand field theory a development of crystal field theory taking covalency into account; Crystal field theory a model that describes the breaking of degeneracies of electronic orbital states; Post-transition metal, a metallic element to the right of the transition metals in the ...
Thus the determination of the periods of oscillation for various applied field directions allows mapping of the Fermi surface. Observation of the dHvA and SdH oscillations requires magnetic fields large enough that the circumference of the cyclotron orbit is smaller than a mean free path. Therefore, dHvA and SdH experiments are usually ...
On the left, a filled pi-orbital on C 2 H 4 overlaps with an empty d-orbital on the metal. On the right, an empty pi-antibonding orbital on C 2 H 4 overlaps with a filled d-orbital on the metal. The Dewar–Chatt–Duncanson model is a model in organometallic chemistry that explains the chemical bonding in transition metal alkene complexes.
N.B. Pilling and R.E. Bedworth [2] suggested in 1923 that metals can be classed into two categories: those that form protective oxides, and those that cannot. They ascribed the protectiveness of the oxide to the volume the oxide takes in comparison to the volume of the metal used to produce this oxide in a corrosion process in dry air.
A heavy metal is any relatively dense metal, either single element or multielement. [46] Magnesium , aluminium and titanium alloys are light metals of significant commercial importance. [ 47 ] Their densities of 1.7, 2.7 and 4.5 g/cm 3 range from 19 to 56% of the densities of other structural metals, [ 48 ] such as iron (7.9) and copper (8.9 ...
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