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The lattice energy of an ionic compound depends strongly upon the charges of the ions that comprise the solid, which must attract or repel one another via Coulomb's Law. More subtly, the relative and absolute sizes of the ions influence Δ H l a t t i c e {\displaystyle \Delta H_{lattice}} .
The Born–Landé equation is a means of calculating the lattice energy of a crystalline ionic compound.In 1918 [1] Max Born and Alfred Landé proposed that the lattice energy could be derived from the electrostatic potential of the ionic lattice and a repulsive potential energy term.
Vectors and planes in a crystal lattice are described by the three-value Miller index notation. This syntax uses the indices h, k, and ℓ as directional parameters. [4] By definition, the syntax (hkℓ) denotes a plane that intercepts the three points a 1 /h, a 2 /k, and a 3 /ℓ, or some multiple thereof. That is, the Miller indices are ...
The Born–Mayer equation is an equation that is used to calculate the lattice energy of a crystalline ionic compound.It is a refinement of the Born–Landé equation by using an improved repulsion term.
The calculated lattice energy gives a good estimation for the Born–Landé equation; the real value differs in most cases by less than 5%. Furthermore, one is able to determine the ionic radii (or more properly, the thermochemical radius) using the Kapustinskii equation when the lattice energy is known.
In quantum field theory, the quantum vacuum state (also called the quantum vacuum or vacuum state) is the quantum state with the lowest possible energy. Generally, it contains no physical particles. The term zero-point field is sometimes used as a synonym for the vacuum state of a quantized field which is completely individual. [clarification ...
Energy levels for an electron in an atom: ground state and excited states. After absorbing energy, an electron may jump from the ground state to a higher-energy excited state. The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system.
Each is by definition the wavevector of a plane wave in the Fourier series of a spatial function which periodicity follows the crystal lattice (e.g., the function representing the electronic density of the crystal), wavefronts of each plane wave in the Fourier series is perpendicular to the plane wave's wavevector , and these wavefronts are ...