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In chemistry, the electrochemical equivalent (Eq or Z) of a chemical element is the mass of that element (in grams) transported by a specific quantity of electricity, usually expressed in grams per coulomb of electric charge. [1] The electrochemical equivalent of an element is measured with a voltameter.
As of the 2019 revision of the SI, the ampere is defined by fixing the elementary charge e to be exactly 1.602 176 634 × 10 −19 C, [6] [9] which means an ampere is an electric current equivalent to 10 19 elementary charges moving every 1.602 176 634 seconds or 6.241 509 074 × 10 18 elementary charges moving in a second.
It is defined by taking the fixed numerical value of the speed of light in vacuum c to be 299 792 458 when expressed in the unit m s −1, where the second is defined in terms of ∆ν Cs." [1] 1 / 10 000 000 of the distance from the Earth's equator to the North Pole measured on the meridian arc through Paris. L kilogram: kg mass
Historically, the mole was defined as the amount of substance in 12 grams of the carbon-12 isotope.As a consequence, the mass of one mole of a chemical compound, in grams, is numerically equal (for all practical purposes) to the mass of one molecule or formula unit of the compound, in daltons, and the molar mass of an isotope in grams per mole is approximately equal to the mass number ...
Faraday discovered that when the same amount of electric current is passed through different electrolytes connected in series, the masses of the substances deposited or liberated at the electrodes are directly proportional to their respective chemical equivalent/equivalent weight (E). [3]
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
At that time, the volt was defined as the potential difference [i.e., what is nowadays called the "voltage (difference)"] across a conductor when a current of one ampere dissipates one watt of power. The "international volt" was defined in 1893 as 1 ⁄ 1.434 of the emf of a Clark cell.
The simplest example given by Thimbleby of a possible problem when using an immediate-execution calculator is 4 × (−5). As a written formula the value of this is −20 because the minus sign is intended to indicate a negative number, rather than a subtraction, and this is the way that it would be interpreted by a formula calculator.