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In thermodynamics, the Joule–Thomson effect (also known as the Joule–Kelvin effect or Kelvin–Joule effect) describes the temperature change of a real gas or liquid (as differentiated from an ideal gas) when it is expanding; typically caused by the pressure loss from flow through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment.
The Thomson effect is an extension of the Peltier–Seebeck model and is credited to Lord Kelvin. Joule heating, the heat that is generated whenever a current is passed through a conductive material, is not generally termed a thermoelectric effect.
The collaboration lasted from 1852 to 1856, its discoveries including the Joule–Thomson effect, sometimes called the Kelvin–Joule effect, and the published results [42] did much to bring about general acceptance of Joule's work and the kinetic theory.
James Joule was born in 1818, the son of Benjamin Joule (1784–1858), a wealthy brewer, and his wife, Alice Prescott, on New Bailey Street in Salford. [3] Joule was tutored as a young man by the famous scientist John Dalton and was strongly influenced by chemist William Henry and Manchester engineers Peter Ewart and Eaton Hodgkinson.
The Joule–Thomson effect, the temperature change of a gas when it is forced through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment. The Gough–Joule effect or the Gow–Joule effect, which is the tendency of elastomers to contract if heated while they are under tension.
The SI unit for heat capacity of an object is joule per kelvin (J/K or J⋅K −1). Since an increment of temperature of one degree Celsius is the same as an increment of one kelvin, that is the same unit as J/°C. The heat capacity of an object is an amount of energy divided by a temperature change, which has the dimension L 2 ⋅M⋅T −2 ...
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On the other hand, real-gas models have to be used near the condensation point of gases, near critical points, at very high pressures, to explain the Joule–Thomson effect, and in other less usual cases. The deviation from ideality can be described by the compressibility factor Z.