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Second-order phase transitions are continuous in the first derivative (the order parameter, which is the first derivative of the free energy with respect to the external field, is continuous across the transition) but exhibit discontinuity in a second derivative of the free energy. [6]
Landau theory (also known as Ginzburg–Landau theory, despite the confusing name [1]) in physics is a theory that Lev Landau introduced in an attempt to formulate a general theory of continuous (i.e., second-order) phase transitions. [2]
Such a quantum phase transition can be a second-order phase transition. [1] Quantum phase transitions can also be represented by the topological fermion condensation quantum phase transition, see e.g. strongly correlated quantum spin liquid. In case of three dimensional Fermi liquid, this transition transforms the Fermi surface into a Fermi volume.
Charge ordering (CO) is a (first- or second-order) phase transition occurring mostly in strongly correlated materials such as transition metal oxides or organic conductors. Due to the strong interaction between electrons, charges are localized on different sites leading to a disproportionation and an ordered superlattice.
The NI transition is a first-order phase transition, albeit it is very weak. The order parameter is the Q {\displaystyle \mathbf {Q} } tensor, which is symmetric, traceless, second-order tensor and vanishes in the isotropic liquid phase.
A tricritical point is a point where a second order phase transition curve meets a first order phase transition curve. The notion was first introduced by Lev Landau in 1937, who referred to the tricritical point as the critical point of the continuous transition.
Based on Landau's previously established theory of second-order phase transitions, Ginzburg and Landau argued that the free energy density of a superconductor near the superconducting transition can be expressed in terms of a complex order parameter field () = | | (), where the quantity | | is a measure of the local density of superconducting electrons () analogous to a quantum mechanical wave ...
The discontinuity in , and other properties, e.g. internal energy, , and entropy,, of the substance, is called a first order phase transition. [12] [13] In order to specify the unique experimentally observed pressure, (), at which it occurs another thermodynamic condition is required, for from Fig.1 it could clearly occur for any pressure in the range .