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Bromic acid, also known as hydrogen bromate, is an oxoacid with the molecular formula HBrO 3.It only exists in aqueous solution. [1] [2] It is a colorless solution that turns yellow at room temperature as it decomposes to bromine.
The nitrogen atom has only 6 electrons assigned to it. One of the lone pairs on an oxygen atom must form a double bond, but either atom will work equally well. Therefore, there is a resonance structure. Tie up loose ends. Two Lewis structures must be drawn: Each structure has one of the two oxygen atoms double-bonded to the nitrogen atom.
For example, NH 3 is a Lewis base, because it can donate its lone pair of electrons. Trimethylborane [(CH 3) 3 B] is a Lewis acid as it is capable of accepting a lone pair. In a Lewis adduct, the Lewis acid and base share an electron pair furnished by the Lewis base, forming a dative bond. [1]
From numbers of equivalent portions of acid bromine formed from the previous reaction, the ratio between oxygen and bromine was calculated, with the exact value of O:Br (0.149975:0.3745), suggesting the acid compound contains two oxygen atom to one bromine atom. Thus, the chemical structure of the acid compound was deducted as HBrO 2. [2]
Instead of defining acid–base reactions in terms of protons or other bonded substances, the Lewis definition defines a base (referred to as a Lewis base) to be a compound that can donate an electron pair, and an acid (a Lewis acid) to be a compound that can receive this electron pair. [23] For example, boron trifluoride, BF 3 is a typical ...
In chemistry, an electron pair or Lewis pair consists of two electrons that occupy the same molecular orbital but have opposite spins. Gilbert N. Lewis introduced the concepts of both the electron pair and the covalent bond in a landmark paper he published in 1916. [1] [2]
Arrow pushing or electron pushing is a technique used to describe the progression of organic chemistry reaction mechanisms. [1] It was first developed by Sir Robert Robinson.In using arrow pushing, "curved arrows" or "curly arrows" are drawn on the structural formulae of reactants in a chemical equation to show the reaction mechanism.
Addition of bromine to water gives hypobromous acid and hydrobromic acid (HBr(aq)) via a disproportionation reaction.. Br 2 + H 2 O HOBr + HBr. In nature, hypobromous acid is produced by bromoperoxidases, which are enzymes that catalyze the oxidation of bromide with hydrogen peroxide: [2] [3]