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The spin transition is an example of transition between two electronic states in molecular chemistry. The ability of an electron to transit from a stable to another stable (or metastable ) electronic state in a reversible and detectable fashion, makes these molecular systems appealing in the field of molecular electronics .
In physics and chemistry, specifically in nuclear magnetic resonance (NMR), magnetic resonance imaging (MRI), and electron spin resonance (ESR), the Bloch equations are a set of macroscopic equations that are used to calculate the nuclear magnetization M = (M x, M y, M z) as a function of time when relaxation times T 1 and T 2 are present.
The conventional definition of the spin quantum number is s = n / 2 , where n can be any non-negative integer. Hence the allowed values of s are 0, 1 / 2 , 1, 3 / 2 , 2, etc. The value of s for an elementary particle depends only on the type of particle and cannot be altered in any known way (in contrast to the spin ...
This solution has found practical applications in physics of Bose-Einstein condensates. [19] Spin clusters interacting with time-dependent magnetic fields. [20] This class of models shows relatively complex behavior of the transition probabilities due to the path interference effects in the semiclassical independent crossing approximation.
In a laboratory setting, the hydrogen line parameters have been more precisely measured as: λ = 21.106 114 054 160 (30) cm ν = 1 420 405 751.768(2) Hz. in a vacuum. [3] This transition is highly forbidden with an extremely small transition rate of 2.9 × 10 −15 s −1, [4] and a mean lifetime of the excited state of around 11 million years. [3]
Schematic equal-time spin correlation functions for ferromagnetic and antiferromagnetic materials both above and below versus the distance normalized by the correlation length, . In all cases, correlations are strongest nearest to the origin, indicating that a spin has the strongest influence on its nearest neighbors.
Each has two electrons of opposite spin in the π* level so that S = 0 and the multiplicity is 2S + 1 = 1 in consequence. In the first excited state, the two π* electrons are paired in the same orbital, so that there are no unpaired electrons. In the second excited state, however, the two π* electrons occupy different orbitals with opposite spin.
Spin crossover (SCO) is a phenomenon that occurs in some metal complexes wherein the spin state of the complex changes due to an external stimulus. The stimuli can include temperature or pressure. [1] Spin crossover is sometimes referred to as spin transition or spin equilibrium behavior. The change in spin state usually involves interchange of ...