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General scheme ionic propagation. Propagating center can be radical, cationic or anionic. In polymer chemistry, ring-opening polymerization (ROP) is a form of chain-growth polymerization in which the terminus of a polymer chain attacks cyclic monomers to form a longer polymer (see figure). The reactive center can be radical, anionic or cationic.
In polymer chemistry, ring-opening metathesis polymerization (ROMP) is a type of chain-growth polymerization involving olefin metathesis. The driving force of the reaction is relief of ring strain in cyclic olefins (e.g. norbornene or cyclopentene). A variety of heterogeneous and homogeneous catalysts have been developed.
Copolymerization is used to modify the properties of manufactured plastics to meet specific needs, for example to reduce crystallinity, modify glass transition temperature, control wetting properties or to improve solubility. [43] It is a way of improving mechanical properties, in a technique known as rubber toughening. Elastomeric phases ...
Examples of monomer systems that undergo step-growth polymerisation. [5] The reactive functional groups are highlighted. Classes of step-growth polymers are: [6] [7] Polyester has high glass transition temperature T g and high melting point T m, good mechanical properties to about 175 °C, good resistance to solvent and chemicals. It can exist ...
Epoxy. A syringe of "5-minute" epoxy glue, containing separate compartments for the epoxy resin and the hardener. Structure of the epoxide group, a reactive functional group present in all epoxy resins. Epoxy is the family of basic components or cured end products of epoxy resins.
Polyethylene terephthalate (or poly (ethylene terephthalate), PET, PETE, or the obsolete PETP or PET-P), is the most common thermoplastic polymer resin of the polyester family and is used in fibres for clothing, containers for liquids and foods, and thermoforming for manufacturing, and in combination with glass fibre for engineering resins. [5]
Polybenzoxazines are a class of halogen-free high-performance polymers. The main applications of polybenzoxazines resins are in fibre-reinforced plastic and as adhesives. They are substitutes of epoxy, phenolic and bismaleimide resins. Because of their superior resistance to chemicals, low flammability, and excellent heat stability, they are ...
The development of coordination polymerization that enables copolymerization with polar monomers is more recent. [4] Examples of monomers that can be incorporated are methyl vinyl ketones, [5] methyl acrylate, [6] and acrylonitrile. [7] Illustrative metallocene-based coordination catalysts
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