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Group 1: Alkali metals Reaction of sodium (Na) and water Reaction of potassium (K) in water. The alkali metals (Li, Na, K, Rb, Cs, and Fr) are the most reactive metals in the periodic table - they all react vigorously or even explosively with cold water, resulting in the displacement of hydrogen.
Metal aqua ions are often involved in the formation of complexes. The reaction may be written as pM x+ (aq) + qL y− → [M p L q] (px-qy)+ In reality this is a substitution reaction in which one or more water molecules from the first hydration shell of the metal ion are replaced by ligands, L. The complex is described as an inner-sphere complex.
The most reactive metals, such as sodium, will react with cold water to produce hydrogen and the metal hydroxide: 2 Na (s) + 2 H 2 O (l) →2 NaOH (aq) + H 2 (g) Metals in the middle of the reactivity series, such as iron , will react with acids such as sulfuric acid (but not water at normal temperatures) to give hydrogen and a metal salt ...
This reaction occurs quantitatively with salts of the alkali-metals at low to moderate concentrations. [citation needed] With salts of divalent metal ions, the aqua-ion will be subject to a dissociation reaction, known as hydrolysis, a name derived from Greek words for water splitting. The first step in this process can be written as [citation ...
The alkali metals also react with water to form strongly alkaline hydroxides and thus should be handled with great care. The heavier alkali metals react more vigorously than the lighter ones; for example, when dropped into water, caesium produces a larger explosion than potassium if the same number of moles of each metal is used.
Solvated electrons are involved in the reaction of alkali metals with water, even though the solvated electron has only a fleeting existence. [10] Below pH = 9.6 the hydrated electron reacts with the hydronium ion giving atomic hydrogen, which in turn can react with the hydrated electron giving hydroxide ion and usual molecular hydrogen H 2. [11]
These reactions are exothermic and the rise in temperature is usually in the order of the reactivity of the different metals. [5] If the reactant in elemental form is not the more reactive metal, then no reaction will occur. Some examples of this would be the reverse. + No Reaction
Lithium oxide (Li 2 O) is the lightest alkali metal oxide and a white solid. It melts at 1570 °C. Sodium oxide (Na 2 O) is a white solid that melts at 1132 °C and decomposes at 1950 °C. It is a component of glass. Potassium oxide (K 2 O) is a pale yellow solid that decomposes at 350 °C.
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