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It forms a hexahydrate with the formula [Al(H 2 O) 6]Cl 3, containing six water molecules of hydration. Both the anhydrous form and the hexahydrate are colourless crystals, but samples are often contaminated with iron(III) chloride, giving them a yellow colour. The anhydrous form is commercially important. It has a low melting and boiling point.
The integral heat of dissolution is defined as a process of obtaining a certain amount of solution with a final concentration. The enthalpy change in this process, normalized by the mole number of solute, is evaluated as the molar integral heat of dissolution. Mathematically, the molar integral heat of dissolution is denoted as
To clarify that it is the gaseous form that is being referred to, the term anhydrous is prefixed to the name of the substance: Gaseous ammonia is generally referred to as anhydrous ammonia, to distinguish it from its solution in water, household ammonia solution, also known as ammonium hydroxide.
A combined IR, Raman, X-ray, and neutron diffraction study of concentrated hydrochloric acid showed that the hydronium ion forms hydrogen bonded complexes with other water molecules. [28] (See Hydronium for further discussion of this issue.) The pK a value of hydrochloric acid in aqueous solution is estimated theoretically to be −5.9. [5]
anhydrous Having or containing no water molecules, referring especially to water of hydration. [4] Because many processes in chemistry are impeded in the presence of water, it is often of critical importance that water-free reagents and techniques are used. Anhydrous compounds tend to gradually absorb water from the atmosphere.
The first solvation shell of a sodium ion dissolved in water. An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, also known as sodium chloride (NaCl), in water would be represented as Na + (aq) + Cl ...
When a carbohydrate is broken into its component sugar molecules by hydrolysis (e.g., sucrose being broken down into glucose and fructose), this is recognized as saccharification. [2] Hydrolysis reactions can be the reverse of a condensation reaction in which two molecules join into a larger one and eject a water molecule. Thus hydrolysis adds ...
Water can sometimes be removed by heat, vacuum, or the presence of anhydrous hydrohalic acid. Anhydrous metal chlorides suitable for preparing other coordination compounds may be dehydrated by treatment with thionyl chloride: [1] [3] MCl n ·xH 2 O + x SOCl 2 → MCl n + x SO 2 + 2x HCl