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Filipstadite is a very rare mineral [4] of the spinel group, with the formula (Mn,Mg)(Sb 5+ 0.5 Fe 3 + 0.5)O 4. [5] It is isometric, [ 3 ] although it was previously thought to be orthorhombic. When compared to a typical spinel, both the octahedral and tetrahedral sites are split due to cation ordering. [ 3 ]
Hercynite is a spinel of regular symmetry and normal cation distribution, but some disorder occurs in its structure. It consists of ferrous (Fe 2+) ions and aluminium ions (Al 3+); however some ferric ions (Fe 3+) may be located in the structure of hercynite. [5] Melting point of this mineral is inbetween 1,692–1,767 °C (3,078–3,213 °F). [6]
Inverse spinel structures have a different cation distribution in that all of the A cations and half of the B cations occupy octahedral sites, while the other half of the B cations occupy tetrahedral sites. An example of an inverse spinel is Fe 3 O 4, if the Fe 2+ (A 2+) ions are d 6 high-spin and the Fe 3+ (B 3+) ions are d 5 high-spin.
The most studied cation–π interactions involve binding between an aromatic π system and an alkali metal or nitrogenous cation. The optimal interaction geometry places the cation in van der Waals contact with the aromatic ring, centered on top of the π face along the 6-fold axis. [3]
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A former TD Bank employee based in Florida was arrested and charged with facilitating money laundering to Colombia, New Jersey's attorney general said on Wednesday, in the first such arrest since ...
Transmission allows the assigning of priorities to torrents and to files within torrents, thus potentially influencing which files download first. It supports the Magnet URI scheme [9] and encrypted connections. It allows torrent-file creation and peer exchange compatible with Vuze and μTorrent.
Former Manhattan Congresswoman Carolyn Maloney was honored for her tireless work on behalf of 9/11 responders at the US Capitol Wednesday — with a new portrait depicting the 78-year-old ...