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Chromium trioxide (also known as chromium(VI) oxide or chromic anhydride) is an inorganic compound with the formula CrO 3. It is the acidic anhydride of chromic acid, and is sometimes marketed under the same name. [6] This compound is a dark-purple solid under anhydrous conditions and bright orange when wet. The substance dissolves in water ...
Chromium oxide may refer to: Chromium(II) oxide, CrO; Chromium(III) oxide, Cr 2 O 3; Chromium dioxide (chromium(IV) oxide), CrO 2, which includes the hypothetical compound chromium(II) chromate; Chromium trioxide (chromium(VI) oxide), CrO 3; Chromium(VI) oxide peroxide, CrO 5; Mixed valence species, such as Cr 8 O 21
Chromium(III) oxide (or chromia) is an inorganic compound with the formula Cr 2 O 3. It is one of the principal oxides of chromium and is used as a pigment. In nature, it occurs as the rare mineral eskolaite. [3]
The Sarett oxidation is an organic reaction that oxidizes primary and secondary alcohols to aldehydes and ketones, respectively, using chromium trioxide and pyridine.Unlike the similar Jones oxidation, the Sarett oxidation will not further oxidize primary alcohols to their carboxylic acid form, neither will it affect carbon-carbon double bonds. [1]
Collins reagent is the complex of chromium(VI) oxide with pyridine in dichloromethane. [2] This metal-pyridine complex, a red solid, is used to oxidize primary alcohols to the corresponding aldehydes and secondary alcohols to the corresponding ketones. This complex is a hygroscopic orange solid. [1]
PCC is used as an oxidant.In particular, it has proven to be highly effective in oxidizing primary and secondary alcohols to aldehydes and ketones, respectively.The reagent is more selective than the related Jones' Reagent, so there is little chance of over-oxidation to form carboxylic acids if acidified potassium permanganate is used as long as water is not present in the reaction mixture.
The Cornforth reagent is prepared by slow addition of a concentrated aqueous solution of chromium trioxide to pyridine. The reaction may cause explosion, which is avoided by thoroughly dissolving the trioxide in water and cooling the solution by ice. The product is filtered, washed with acetone and dried, yielding an orange powder.
A trioxide is a compound with three oxygen atoms. For metals with the M 2 O 3 formula there are several common structures. Al 2 O 3 , Cr 2 O 3 , Fe 2 O 3 , and V 2 O 3 adopt the corundum structure .