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This reagent is generated by treating 9-BBN with α-pinene. [2] This sterically crowded chiral trialkylborane can stereoselectively reduce aldehydes in what is known as the Midland Alpine borane reduction, or simply the Midland reduction. [3] C 8 H 12 B-pinanyl + RCDO → C 8 H 12 BOCHDR + (+)-d-pinene. Hydrolysis of the resulting borinic ester ...
In the same year, M. M. Midland discovered B-3-alpha-pinanyl-9-BBN as the reducing agent, which could be easily available by reacting (+)-alpha-pinene with 9-BBN. The new reducing agent was later commercialized by Aldrich Co. under the name Alpine Borane and the asymmetric reduction of carbonyl groups with either enantiomer of Alpine-Borane is ...
9-Borabicyclo[3.3.1]nonane or 9-BBN is an organoborane compound. This colourless solid is used in organic chemistry as a hydroboration reagent. The compound exists as a hydride-bridged dimer, which easily cleaves in the presence of reducible substrates. [1] 9-BBN is also known by its nickname 'banana borane'. [2]
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9-硼二环[3.3.1]壬烷 Metadata This file contains additional information, probably added from the digital camera or scanner used to create or digitize it.
The Northrop Grumman B-21 Raider is an American strategic bomber in development for the United States Air Force (USAF) by Northrop Grumman. Part of the Long Range Strike Bomber (LRS-B) program, it is to be a stealth intercontinental strategic bomber that can deliver conventional and thermonuclear weapons .
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At the time it was the first Passat to be built on a Volkswagen-designed platform, rather than sharing one with an Audi saloon. The Passat B3 was designed by Volkswagen's design chief, Herbert Schäfer and, unlike equivalent Audi models, now featured a space-saving transversely mounted engine (a configuration from which future Passat models would retreat in 1996).