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Defining equation (physical chemistry) List of equations in classical mechanics; Table of thermodynamic equations; List of equations in wave theory;
Hess's law states that the change of enthalpy in a chemical reaction is the same regardless of whether the reaction takes place in one step or several steps, provided the initial and final states of the reactants and products are the same. Enthalpy is an extensive property, meaning that its value is proportional to the system size. [4]
However, if one searches for real solutions, there are two solutions, √ 2 and – √ 2; in other words, the solution set is {√ 2, − √ 2}. When an equation contains several unknowns, and when one has several equations with more unknowns than equations, the solution set is often infinite. In this case, the solutions cannot be listed.
[4] Perhaps the greatest success of the kinetic theory of gases, as it came to be called, was the discovery that for gases, the temperature as measured on the Kelvin (absolute) temperature scale is directly proportional to the average kinetic energy of the gas molecules. Graham's law for diffusion could thus be understood as a consequence of ...
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
where P is the pressure of the gas, V is the volume of the gas, and k is a constant for a particular temperature and amount of gas.. Boyle's law states that when the temperature of a given mass of confined gas is constant, the product of its pressure and volume is also constant.
To solve this kind of equation, the technique is add, subtract, multiply, or divide both sides of the equation by the same number in order to isolate the variable on one side of the equation. Once the variable is isolated, the other side of the equation is the value of the variable. [37] This problem and its solution are as follows: Solving for x
Using simple algebra on equations , , and yields the result: = or =, where stands for the Boltzmann constant. Another equivalent result, using the fact that n R = N k B {\displaystyle nR=Nk_{\text{B}}} , where n is the number of moles in the gas and R is the universal gas constant , is: P V = n R T , {\displaystyle PV=nRT,} which is known as ...
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