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Halfway between each equivalence point, at 7.5 mL and 22.5 mL, the pH observed was about 1.5 and 4, giving the pK a. In weak monoprotic acids , the point halfway between the beginning of the curve (before any titrant has been added) and the equivalence point is significant: at that point, the concentrations of the two species (the acid and ...
The equivalence point, or stoichiometric point, of a chemical reaction is the point at which chemically equivalent quantities of reactants have been mixed. For an acid-base reaction the equivalence point is where the moles of acid and the moles of base would neutralize each other according to the chemical reaction.
A suitable pH indicator must be chosen in order to detect the end point of the titration. [10] The colour change or other effect should occur close to the equivalence point of the reaction so that the experimenter can accurately determine when that point is reached. The pH of the equivalence point can be estimated using the following rules:
A Gran plot (also known as Gran titration or the Gran method) is a common means of standardizing a titrate or titrant by estimating the equivalence volume or end point in a strong acid-strong base titration or in a potentiometric titration.
The pH at the end-point or equivalence point in a titration may be calculated as follows. At the end-point the acid is completely neutralized so the analytical hydrogen ion concentration, T H, is zero and the concentration of the conjugate base, A −, is equal to the analytical or formal concentration T A of the acid: [A −] = T A.
A graph of potential against volume added can be drawn and the end point of the reaction is halfway between the jump in voltage. E cell depends on the concentration of the interested ions with which the indicator electrode is in contact. For example, the electrode reaction may be + +
Amperometric titration refers to a class of titrations in which the equivalence point is determined through measurement of the electric current produced by the titration reaction. It is a form of quantitative analysis .
The normality of a solution depends on the equivalence factor f eq for a particular reaction, which presents two possible sources of ambiguity – namely, f eq depends on the choice of reaction as well as which chemical species of the reaction is being discussed (e.g., acid/base species, redox species, precipitating salts, isotopes exchanged ...