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Arsenic contamination of ground water is found in many countries throughout the world, including the US. [2] The World Health Organization recommends limiting arsenic concentrations in water to 10 μg/L, although this is often an unattainable goal for many problem areas due to the difficult nature of removing arsenic from water sources. [3]
The arsenic (As) cycle is the biogeochemical cycle of natural and anthropogenic exchanges of arsenic terms through the atmosphere, lithosphere, pedosphere, hydrosphere, and biosphere. Although arsenic is naturally abundant in the Earth's crust, long-term exposure and high concentrations of arsenic can be detrimental to human health. [1] [2]
Throughout the years, many studies reported dose-dependent effects of arsenic in drinking water and skin cancer. In order to prevent new cases and death from cancerous and non-cancerous diseases, the Safe Drinking Water Act directed the Environmental Protection Agency to revise arsenic's levels and specified the maximum contaminant level (MCL).
Bioremediation of ground water contaminated with arsenic aims to convert arsenite, the toxic form of arsenic to humans, to arsenate. Arsenate (+5 oxidation state) is the dominant form of arsenic in surface water, while arsenite (+3 oxidation state) is the dominant form in hypoxic to anoxic environments.
Groundwater pollution (also called groundwater contamination) occurs when pollutants are released to the ground and make their way into groundwater.This type of water pollution can also occur naturally due to the presence of a minor and unwanted constituent, contaminant, or impurity in the groundwater, in which case it is more likely referred to as contamination rather than pollution.
Arsenic is a common natural contaminant of well water and is highly carcinogenic. Iron oxide adsorption treatment for arsenic in groundwater is a commonly practiced removal process which involves the chemical treatment of arsenic species such that they adsorb onto iron oxides and create larger particles that may be filtered out of the water stream.
Arsenic poisoning is a global problem arising from naturally occurring arsenic in ground water. The evidence that arsenic may be a beneficial nutrient at trace levels below the background to which living organisms are normally exposed has been reviewed. [3]
For instance, if arsenic is detected in tap water from a given well, the detected concentrations should be compared with regulatory thresholds for allowable levels of arsenic in drinking water. If the detected levels are consistently lower than these limits, arsenic may not be a chemical of potential concern for the purposes of this risk ...