Search results
Results from the WOW.Com Content Network
For example, in the symmetric group shown above, where ord(S 3) = 6, the possible orders of the elements are 1, 2, 3 or 6. The following partial converse is true for finite groups: if d divides the order of a group G and d is a prime number, then there exists an element of order d in G (this is sometimes called Cauchy's theorem).
In organic chemistry, neighbouring group participation (NGP, also known as anchimeric assistance) has been defined by the International Union of Pure and Applied Chemistry (IUPAC) as the interaction of a reaction centre with a lone pair of electrons in an atom or the electrons present in a sigma or pi bond contained within the parent molecule but not conjugated with the reaction centre.
An example of a simple chain reaction is the thermal decomposition of acetaldehyde (CH 3 CHO) to methane (CH 4) and carbon monoxide (CO). The experimental reaction order is 3/2, [4] which can be explained by a Rice-Herzfeld mechanism. [5] This reaction mechanism for acetaldehyde has 4 steps with rate equations for each step :
In organic chemistry, a group transfer reaction is a class of the pericyclic reaction where one or more groups of atoms is transferred from one molecule to another. Group transfer reactions can sometimes be difficult to identify when separate reactant molecules combine into a single product molecule (like in the ene reaction).
One of the non-abelian groups is the semidirect product of a normal cyclic subgroup of order p 2 by a cyclic group of order p. The other is the quaternion group for p = 2 and a group of exponent p for p > 2. Order p 4: The classification is complicated, and gets much harder as the exponent of p increases.
1.2 Leaving groups. ... In organic chemistry, a cross-coupling reaction is a reaction where two different fragments are joined. Cross-couplings are a subset of the ...
A single-displacement reaction, also known as single replacement reaction or exchange reaction, is an archaic concept in chemistry. It describes the stoichiometry of some chemical reactions in which one element or ligand is replaced by atom or group. [1] [2] [3] It can be represented generically as: + +
[1] [2] This enables systematic prediction of chemical reactions and behavior of chemical compounds and the design of chemical synthesis. The reactivity of a functional group can be modified by other functional groups nearby. Functional group interconversion can be used in retrosynthetic analysis to plan organic synthesis. A functional group is ...