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  2. Reaction mechanism - Wikipedia

    en.wikipedia.org/wiki/Reaction_mechanism

    An example of a simple chain reaction is the thermal decomposition of acetaldehyde (CH 3 CHO) to methane (CH 4) and carbon monoxide (CO). The experimental reaction order is 3/2, [4] which can be explained by a Rice-Herzfeld mechanism. [5] This reaction mechanism for acetaldehyde has 4 steps with rate equations for each step :

  3. Neighbouring group participation - Wikipedia

    en.wikipedia.org/wiki/Neighbouring_group...

    In organic chemistry, neighbouring group participation (NGP, also known as anchimeric assistance) has been defined by the International Union of Pure and Applied Chemistry (IUPAC) as the interaction of a reaction centre with a lone pair of electrons in an atom or the electrons present in a sigma or pi bond contained within the parent molecule but not conjugated with the reaction centre.

  4. Cross-coupling reaction - Wikipedia

    en.wikipedia.org/wiki/Cross-coupling_reaction

    1.2 Leaving groups. ... In organic chemistry, a cross-coupling reaction is a reaction where two different fragments are joined. Cross-couplings are a subset of the ...

  5. Functional group - Wikipedia

    en.wikipedia.org/wiki/Functional_group

    Functional group interconversion can be used in retrosynthetic analysis to plan organic synthesis. A functional group is a group of atoms in a molecule with distinctive chemical properties, regardless of the other atoms in the molecule. The atoms in a functional group are linked to each other and to the rest of the molecule by covalent bonds ...

  6. Chemical reaction - Wikipedia

    en.wikipedia.org/wiki/Chemical_reaction

    For example, when barium chloride (BaCl 2) and magnesium sulfate (MgSO 4) react, the SO 4 2− anion switches places with the 2Cl − anion, giving the compounds BaSO 4 and MgCl 2. Another example of a double displacement reaction is the reaction of lead(II) nitrate with potassium iodide to form lead(II) iodide and potassium nitrate : Pb ( NO 3 ...

  7. Order (group theory) - Wikipedia

    en.wikipedia.org/wiki/Order_(group_theory)

    For example, in the symmetric group shown above, where ord(S 3) = 6, the possible orders of the elements are 1, 2, 3 or 6. The following partial converse is true for finite groups: if d divides the order of a group G and d is a prime number, then there exists an element of order d in G (this is sometimes called Cauchy's theorem).

  8. No. 9 Ole Miss loses to Florida on awful Jaxson Dart ...

    www.aol.com/sports/no-9-ole-miss-loses-204047839...

    Montrell Johnson Jr.'s 5-yard touchdown run with 7:40 remaining in the fourth quarter gave Florida a 24-17 win over No. 9 Ole Miss on Saturday in Gainesville. Ole Miss had a chance to tie the game ...

  9. Benson group increment theory - Wikipedia

    en.wikipedia.org/wiki/Benson_group_increment_theory

    The 2' carbon of the butyl group would be C−(C) 3 (H) because it is a tertiary carbon (connecting to three other carbon atoms). The final calculation comes from the CH 3 groups connected to the 2' carbon; C−(C)(H) 3. The total calculations add to −5.15 kcal/mol (−21.6 kJ/mol), which is identical to the experimental value, which can be ...