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The word "titration" descends from the French word titrer (1543), meaning the proportion of gold or silver in coins or in works of gold or silver; i.e., a measure of fineness or purity. Tiltre became titre, [4] which thus came to mean the "fineness of alloyed gold", [5] and then the "concentration of a substance in a given sample". [6]
A blank value in analytical chemistry is a measurement of a blank. The reading does not originate from a sample, but the matrix effects , reagents and other residues . These contribute to the sample value in the analytical measurement and therefore have to be subtracted.
The term also has two other, conflicting meanings. In titration, the titer is the ratio of actual to nominal concentration of a titrant, e.g. a titer of 0.5 would require 1/0.5 = 2 times more titrant than nominal. This is to compensate for possible degradation of the titrant solution.
In analytical chemistry, a standard solution (titrant or titrator) is a solution containing an accurately known concentration.Standard solutions are generally prepared by dissolving a solute of known mass into a solvent to a precise volume, or by diluting a solution of known concentration with more solvent. [1]
Where HV is the hydroxyl value; V B is the amount (ml) potassium hydroxide solution required for the titration of the blank; V acet is the amount (ml) of potassium hydroxide solution required for the titration of the acetylated sample; W acet is the weight of the sample (in grams) used for acetylation; N is the normality of the titrant; 56.1 is ...
Acid–base titration is also utilized in the analysis of acid rain effects on soil and water bodies, contributing to the overall understanding and management of environmental quality. [24] The method's prevision and reliability make it a valuable tool in safeguarding ecosystems and assessing the impact of human activities on natural water ...
A blank solution is a solution containing little to no analyte of interest, [1] usually used to calibrate instruments such as a colorimeter. According to the EPA, the "primary purpose of blanks is to trace sources of artificially introduced contamination." [2] Different types of blanks are used to identify the source of contamination in the ...
(B – S) is the difference between the volumes, in mL, of sodium thiosulfate required for the blank and for the sample, respectively; N is the normality of sodium thiosulfate solution in Eq/ L; 12.69 is the conversion factor from mEq sodium thiosulfate to grams of iodine (the molecular weight of iodine is 126.9 g/mol);