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Most toothpastes contains between 0.22% (1,000 ppm) and 0.312% (1,450 ppm) fluoride, usually in the form of sodium fluoride, stannous fluoride, or sodium monofluorophosphate (MFP). Frequent use of toothpaste with 1,100 ppm fluoride content enhances the remineralization of enamel and inhibits the demineralization of enamel and root surfaces. [34]
Fluoride has a high tendency to react with the calcium hydroxyapatite Ca10(PO4)6(OH)2 in tooth enamel due to its high affinity to metals. [8] [10] It subsequently replaces the hydroxide group in hydroxyapatite to precipitate calcium fluorapatite Ca5(PO4)3)F. [8] These fluorapatite precipitations scavenge excess phosphate and calcium in the saliva to form a supersaturated solution for ...
The additional fluoride in toothpaste has beneficial effects on the formation of dental enamel and bones. Sodium fluoride (NaF) is the most common source of fluoride, but stannous fluoride (SnF 2), and sodium monofluorophosphate (Na 2 PO 3 F) are also used. [12]
Sodium monofluorophosphate is produced industrially by the reaction of sodium fluoride with sodium metaphosphate: [2] NaPO 3 + NaF → Na 2 PO 3 F. The process involves scission of a pyrophosphate bond, analogous to hydrolysis. SMFP can also be prepared by treating tetrasodium pyrophosphate or disodium phosphate with hydrogen fluoride. [2]
Regular use of a fluoridated toothpaste has been shown to provide a significant source of fluoride to the mouth by the means of direct fluoride contact to tooth structure. [20] The types of fluoride added to toothpaste include: sodium fluoride , sodium monofluorophosphate (MFP), and stannous fluoride .
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