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In glucose polymers such as starch and starch-derivatives like glucose syrup, maltodextrin and dextrin the macromolecule begins with a reducing sugar, a free aldehyde. When starch has been partially hydrolyzed the chains have been split and hence it contains more reducing sugars per gram.
The DE can be calculated as 100*(180 / Molecular mass( glucose polymer)). In this example the DE is calculated as 100*(180/(180*2-18*1)) = 52. Sucrose actually has a DE of zero even though it is a disaccharide, because both reducing groups of the monosaccharides that make it are connected, so there are no remaining reducing groups.
Starch (a polymer of glucose) is used as a storage polysaccharide in plants, being found in the form of both amylose and the branched amylopectin. In animals, the structurally similar glucose polymer is the more densely branched glycogen, sometimes called "animal starch". Glycogen's properties allow it to be metabolized more quickly, which ...
Like glucose, maltose is a reducing sugar, because the ring of one of the two glucose units can open to present a free aldehyde group; the other one cannot because of the nature of the glycosidic bond. Maltose can be broken down to glucose by the maltase enzyme, which catalyses the hydrolysis of the glycosidic bond. [citation needed]
Polydextrose is a synthetic polymer of glucose. [1] It is a food ingredient classified as soluble fiber by the US FDA as well as Health Canada , as of April 2013 [update] . It is frequently used to increase the dietary fiber content of food, to replace sugar, and to reduce calories and fat content.
For example, a glucose polymer is named glucan, a mannose polymer is named mannan, and a galactose polymer is named galactan. When the glycosidic linkages and configurations of the monosaccharides are known, they may be included as a prefix to the name, with the notation for glycosidic linkages preceding the symbols designating the ...
Reducing disaccharides, in which one monosaccharide, the reducing sugar of the pair, still has a free hemiacetal unit that can perform as a reducing aldehyde group; lactose, maltose and cellobiose are examples of reducing disaccharides, each with one hemiacetal unit, the other occupied by the glycosidic bond, which prevents it from acting as a ...
Amylose A is a parallel double-helix of linear chains of glucose. Amylose is made up of α(1→4) bound glucose molecules. The carbon atoms on glucose are numbered, starting at the aldehyde (C=O) carbon, so, in amylose, the 1-carbon on one glucose molecule is linked to the 4-carbon on the next glucose molecule (α(1→4) bonds). [3]
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