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To finish the items, the process is run for approximately 20 hours at 200 V with a starting current of 300 A (60 kW) for a furnace approximately 9 meters long by 35 cm in width and 45 cm in depth, and the resistance drops as the carbon heats due to a negative temperature coefficient, causing the current to increase. [2] Cool down takes weeks.
Graphitization generally occurs at high temperatures (up to 3,000 °C (5,430 °F)), and can be accelerated by catalysts such as iron or nickel. [ 2 ] When carbonaceous material is exposed to high temperatures for an extended period of time, the carbon atoms begin to rearrange and form layered crystal planes.
At high temperatures, the forward reaction becomes endergonic, favoring the reverse reaction toward CO, even though the forward reaction is still exothermic. The effect of temperature on the extent of the Boudouard reaction is indicated better by the value of the equilibrium constant than by the standard free energy of reaction .
The Chinese HTR-PM, a 250 MW t Generation IV HTGR, features an outlet temperature of 750 °C (1,380 °F). [6] As of 2024, it is the only high-temperature small modular reactor currently in operation. Likewise, geothermal heat sources often have relatively low temperatures, sometimes even requiring binary cycles for electricity generation. [7] [8]
Diagram of a Castner lengthwise graphitization furnace. a - Mixture of Coke and Sand, b - Bricks, c - Carbon Electrodes, d - Refractory Material, e - Rods to Graphitize, f - Granulated Coke File usage
The burner in the vertical, cylindrical furnace as above, is located in the floor and fires upward. Some furnaces have side fired burners, such as in train locomotives. The burner tile is made of high temperature refractory and is where the flame is contained. Air registers located below the burner and at the outlet of the air blower are ...
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