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  2. Trichlorosilane - Wikipedia

    en.wikipedia.org/wiki/Trichlorosilane

    Trichlorosilane is a reagent in the conversion of benzoic acids to toluene derivatives. In the first step of a two-pot reaction, the carboxylic acid is first converted to the trichlosilylbenzyl compound. In the second step, the benzylic silyl derivative is converted to the toluene derivative with base. [7]

  3. Chlorosilane - Wikipedia

    en.wikipedia.org/wiki/Chlorosilane

    The methylchlorosilanes react with water to produce hydrogen chloride, giving siloxanes. In the case of trimethylsilyl chloride, the hydrolyzed product is hexamethyldisiloxane: 2 ((CH 3) 3 SiCl + H 2 O → [(CH 3) 3 Si] 2 O + 2 HCl. The analogous reaction of dimethyldichlorosilane gives siloxane polymers or rings: n (CH 3) 2 SiCl 2 + n H 2 O ...

  4. Trimethylsilyl chloride - Wikipedia

    en.wikipedia.org/wiki/Trimethylsilyl_chloride

    TMSCl is reactive toward nucleophiles, resulting in the replacement of the chloride. In a characteristic reaction of TMSCl, the nucleophile is water, resulting in hydrolysis to give the hexamethyldisiloxane: + + The related reaction of trimethylsilyl chloride with alcohols can be exploited to produce anhydrous solutions of hydrochloric acid in alcohols, which find use in the mild synthesis of ...

  5. Nylon rope trick - Wikipedia

    en.wikipedia.org/wiki/Nylon_Rope_Trick

    Acid Chloride Preparative Route for Nylon-6,10, which is often used in the nylon rope trick. The nylon rope trick is a scientific demonstration that illustrates some of the fundamental chemical principles of step-growth polymerization and provides students and other observers with a hands-on demonstration of the preparation of a synthetic polymer.

  6. Methyltrichlorosilane - Wikipedia

    en.wikipedia.org/wiki/Methyltrichlorosilane

    Methyltrichlorosilane vapor reacts with water on surfaces to give a thin layer of methylpolysiloxane, which changes the contact angle of the surface to water. This effect arises because of the oriented layer of methyl groups, making a water-repellent film. [ 4 ]

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  8. Moskowitz, Florida Democrat, throws cold water on his ...

    www.aol.com/moskowitz-florida-democrat-throws...

    Rep. Jared Moskowitz, D-Fla., shut down rumors Tuesday that he could be leaving Capitol Hill to join President-elect Donald Trump's incoming administration. Moskowitz was rumored to be Trump's top ...

  9. Don Johnson shares rare photo with all 5 children on his 75th ...

    www.aol.com/don-johnson-shares-rare-photo...

    Don Johnson is basking in all the family love. The "Miami Vice" star celebrated his 75th birthday with his children, including Dakota Johnson.