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1-Naphthol, or α-naphthol, is a organic compound with the formula C 10 H 7 OH. It is a fluorescent white solid. 1-Naphthol differs from its isomer 2-naphthol by the location of the hydroxyl group on the naphthalene ring. The naphthols are naphthalene homologues of phenol. Both isomers are soluble in simple organic solvents. They are precursors ...
Naphthalene is a major component of some mothballs.It repels moths as well as some animals. [citation needed]Since mothballs that contain naphthalene are considered hazards, safer alternatives have been developed, such as the use of 1,4-dichlorobenzene, however, 1,4-dichlorobenzene has been declared as a potential neurotoxin. 1,4-dichlorobenzene has been linked to potentially causing ...
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Both naphthalene and 1,4-dichlorobenzene undergo sublimation, meaning that they transition from a solid state directly into a gas; this gas is toxic to moths and moth larvae. [ 1 ] Due to the health risks of 1,4-dichlorobenzene, and flammability of naphthalene, other substances like camphor are sometimes used.
2-Naphthol, or β-naphthol, is a fluorescent colorless (or occasionally yellow) crystalline solid with the formula C 10 H 7 OH. It is an isomer of 1-naphthol, differing by the location of the hydroxyl group on the naphthalene ring. The naphthols are naphthalene homologues of phenol, but more reactive.
The bonds C1−C2, C3−C4, C5−C6 and C7−C8 are about 1.37 Å (137 pm) in length, whereas the other carbon–carbon bonds are about 1.42 Å (142 pm) long. This difference, established by X-ray diffraction , [ 21 ] is consistent with the valence bond model in naphthalene and in particular, with the theorem of cross-conjugation .
Carbaryl is often inexpensively produced by direct reaction of methyl isocyanate with 1-naphthol. [5]C 10 H 7 OH + CH 3 NCO → C 10 H 7 OC(O)NHCH 3. Alternatively, 1-naphthol can be treated with excess phosgene to produce 1-naphthyl chloroformate, which is then converted to carbaryl by reaction with methylamine. [5]
Methylamine (1) reacts with phosgene (2) to produce methyl isocyanate (3), which in turn reacts with 1-naphthol (4) to yield carbaryl (5). By early December 1984, most of the plant's MIC related safety systems were malfunctioning and many valves and lines were in poor condition.