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Poly(2,6-diphenylphenylene oxide) is a low bleeding material with a low level of impurities, and has a high thermal stability (up to 350 °C). Before use poly(2,6-diphenylphenylene oxide) should be thermally conditioned with a high purity gas at elevated temperatures to remove any residual components.
The simplest member of the phenyl ether family is diphenyl ether (DPE), also called diphenyl oxide, the structure of which is provided in Figure 4. Low molecular weight polyphenyl ethers and thioethers are used in a variety of applications, and include high-vacuum devices, optics, electronics, and in high-temperature and radiation-resistant ...
Poly(p-phenylene oxide) (PPO), poly(p-phenylene ether) (PPE), poly(oxy-2,6-dimethyl-1,4-phenylene), often referred to simply as polyphenylene oxide, is a high-temperature thermoplastic with the general formula (C 8 H 8 O) n. It is rarely used in its pure form due to difficulties in processing.
Diphenyl ether was discovered by Heinrich Limpricht and Karl List in 1855, when they reproduced Carl Ettling's destructive distillation of copper benzoate and separated it from the low-melting oily distillate components ignored by previous researchers. They named the compound phenyl oxide (German: Phenyloxyd) and studied some of its derivatives ...
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In organic chemistry, the phenylene group (−C 6 H 4 −) is based on a di-substituted benzene ring . For example, poly(p-phenylene) is a polymer built up from para-phenylene repeating units. [1] The phenylene group has three structural isomers, based on which hydrogens are substituted: para-phenylene, meta-phenylene, and ortho-phenylene.
Poly(p-phenylene) (PPP) is made of repeating p-phenylene units, which act as the precursor to a conducting polymer of the rigid-rod polymer family. The synthesis of PPP has proven challenging, but has been accomplished through excess polycondensation with the Suzuki coupling method.
In the laboratory, diphenylphosphine is a common intermediate. It can be deprotonated to give diphenylphosphide derivatives: [2] Ph 2 PH + n BuLi → Ph 2 PLi + n BuH. The preparation of phosphine ligands, Wittig-Horner reagents, and phosphonium salts are commonly accomplished by alkylating diphenylphosphine.