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In chemical physics and physical chemistry, chemical affinity is the electronic property by which dissimilar chemical species are capable of forming chemical compounds. [1] Chemical affinity can also refer to the tendency of an atom or compound to combine by chemical reaction with atoms or compounds of unlike composition.
This local increase in order is, however, only possible at the expense of an entropy increase in the surroundings; here more disorder must be created. [9] [15] The conditioner of this statement suffices that living systems are open systems in which both heat, mass, and or work may transfer into or out of the system. Unlike temperature, the ...
Avidity (functional affinity) is the accumulated strength of multiple affinities. [2] For example, IgM is said to have low affinity but high avidity because it has 10 weak binding sites for antigen as opposed to the 2 stronger binding sites of IgG, IgE and IgD with higher single binding affinities. [citation needed]
Therefore, the thermodynamic entropy, which is proportional to the marginal entropy, must also increase with time [8] (note that "not too long" in this context is relative to the time needed, in a classical version of the system, for it to pass through all its possible microstates—a time that can be roughly estimated as , where is the time ...
The electron affinity of molecules is a complicated function of their electronic structure. For instance the electron affinity for benzene is negative, as is that of naphthalene, while those of anthracene, phenanthrene and pyrene are positive. In silico experiments show that the electron affinity of hexacyanobenzene surpasses that of fullerene. [5]
Affinity, the UK's first road-legal solar car, built by Cambridge University Eco Racing; Affinity (mathematics), an affine transformation preserving collinearity; Affinity (pharmacology), a characterisation of protein-ligand binding strength; Affinity (sociology), a shared interest and commitment between persons in groups and/or willingness to ...
The theory of evolution deals primarily with changes in successive generations over time after life has already originated. [132] The scientific model concerned with the origin of the first organisms from organic or inorganic molecules is known as abiogenesis , and the prevailing theory for explaining the early development of the universe is ...
This law of entropy increase quantifies the reduction in the capacity of an isolated compound thermodynamic system to do thermodynamic work on its surroundings, or indicates whether a thermodynamic process may occur. For example, whenever there is a suitable pathway, heat spontaneously flows from a hotter body to a colder one.