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The thiocarbonate moiety can be functionalized at the R-group for end group analysis. The end group is a result of the propagation of chain-transfer agents during the free-radical polymerization process. The end groups can subsequently be modified by the reaction of the thiocarbonylthio compounds with nucleophiles and ionic reducing agents. [11]
The subunits that make up each of these structures are identified, i.e., the largest divalent groups that can be named using IUPAC nomenclature of organic chemistry. In the example, the two-carbon ethylidene unit is longer than two separate one-carbon methanediyl units. Figure 1. The order of subunit precedence.
If the alkyl group is not attached at the end of the chain, the bond position to the ester group is suffixed before "-yl": CH 3 CH 2 CH(CH 3)OOCCH 2 CH 3 may be called butan-2-yl propanoate or butan-2-yl propionate. [citation needed]. The prefix form is "oxycarbonyl-" with the (R') group preceding.
Quantities, Units and Symbols in Physical Chemistry, also known as the Green Book, is a compilation of terms and symbols widely used in the field of physical chemistry. It also includes a table of physical constants , tables listing the properties of elementary particles , chemical elements , and nuclides , and information about conversion ...
It is generally considered the average length for a carbon–carbon single bond, but is also the largest bond length that exists for ordinary carbon covalent bonds. Since one atomic unit of length (i.e., a Bohr radius) is 52.9177 pm, the C–C bond length is 2.91 atomic units, or approximately three Bohr radii long.
In organic chemistry, a vinyl group (abbr. Vi; [1] IUPAC name: ethenyl group [2]) is a functional group with the formula −CH=CH 2. It is the ethylene (IUPAC name: ethene) molecule (H 2 C=CH 2) with one fewer hydrogen atom. The name is also used for any compound containing that group, namely R−CH=CH 2 where R is any other group of atoms.
This naming method generally follows established IUPAC organic nomenclature. Hydrides of the main group elements (groups 13–17) are given the base name ending with -ane, e.g. borane (B H 3), oxidane (H 2 O), phosphane (P H 3) (Although the name phosphine is also in common use, it is not recommended by
A full edition was published in 1979, [1] an abridged and updated version of which was published in 1993 as A Guide to IUPAC Nomenclature of Organic Compounds. [2] Both of these are now out-of-print in their paper versions, but are available free of charge in electronic versions.