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A molecular sieve is a material with pores (voids or holes), having uniform size comparable to that of individual molecules, linking the interior of the solid to its exterior. These materials embody the molecular sieve effect, the preferential sieving of molecules larger than the pores.
Pentasil-zeolites are defined by their structure type, and more specifically by their X-ray diffraction patterns. ZSM -5 is the trade name of a pentasil-zeolite. As early as 1967, Argauer and Landolt worked out parameters for the synthesis of pentasilzeolites, particularly those relating to the following molar ratios: OH − /SiO 2 = 0.07–10, SiO 2 /Al 2 O 3 = 5–100, H 2 O/SiO 2 = 1–240. [1]
As a result, the pore entrance of LTA is an 8-ring (0.41 nm [3]) and belongs to the small pore zeolite, while the pore entrance of FAU is a 12-ring (0.74 nm [3]) and belongs to the large pore zeolite, respectively. Materials with a 10-ring are called medium pore zeolites, a typical example being ZSM-5 (MFI).
The presence of defects can make these membranes far less effective, and it is difficult to produce defect free zeolite membranes. [4] There are several mechanisms of transport that govern the separation of molecules by zeolite membranes. The main mechanisms for separation by zeolite membranes are molecular sieving, diffusion, and adsorption.
Size-exclusion chromatography, also known as molecular sieve chromatography, [1] is a chromatographic method in which molecules in solution are separated by their shape, and in some cases size. [2] It is usually applied to large molecules or macromolecular complexes such as proteins and industrial polymers . [ 3 ]
Framework structure of SSZ-13 with CHA topology. SSZ-13 (framework type code CHA) is a high-silica aluminosilicate zeolite possessing 0.38 × 0.38 nm micropores. [1] It belongs to the ABC-6 family of zeolites as well as offretite, cancrinite, erionite and other related small-pore zeolites. [2]
In 1956 Flanigen began working on molecular sieves. [4] Molecular sieves are crystal compounds with molecular sized pores that can filter or separate very complex substances. Edith Flanigen is best known as the inventor of zeolite Y, a specific molecular sieve. Zeolite Y was a certain type of molecular sieve that could refine petroleum. Zeolite ...
Faujasite (FAU-type zeolite) is a mineral group in the zeolite family of silicate minerals.The group consists of faujasite-Na, faujasite-Mg and faujasite-Ca. They all share the same basic formula (Na 2,Ca,Mg) 3.5 [Al 7 Si 17 O 48]·32(H 2 O) by varying the amounts of sodium, magnesium and calcium. [1]
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