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Latent heat is associated with the change of phase of atmospheric or ocean water, vaporization, condensation, freezing or melting, whereas sensible heat is energy transferred that is evident in change of the temperature of the atmosphere or ocean, or ice, without those phase changes, though it is associated with changes of pressure and volume.
Enthalpies of melting and boiling for pure elements versus temperatures of transition, demonstrating Trouton's rule. In thermodynamics, the enthalpy of fusion of a substance, also known as (latent) heat of fusion, is the change in its enthalpy resulting from providing energy, typically heat, to a specific quantity of the substance to change its state from a solid to a liquid, at constant pressure.
Freezing is a phase transition in which a liquid turns into a solid when its temperature is lowered below its freezing point. [ 1 ] [ 2 ] For most substances, the melting and freezing points are the same temperature; however, certain substances possess differing solid-liquid transition temperatures.
In all cases the water supercooled, reaching a temperature of typically −6 to −18 °C (21 to 0 °F; 267 to 255 K) before spontaneously freezing. Considerable random variation was observed in the time required for spontaneous freezing to start and in some cases this resulted in the water which started off hotter (partially) freezing first. [11]
Similar to the Kelvin scale, which was first proposed in 1848, [1] zero on the Rankine scale is absolute zero, but a temperature difference of one Rankine degree (°R or °Ra) is defined as equal to one Fahrenheit degree, rather than the Celsius degree used on the Kelvin scale.
The kinetic energy of particle motion is just one contributor to the total thermal energy in a substance; another is phase transitions, which are the potential energy of molecular bonds that can form in a substance as it cools (such as during condensing and freezing). The thermal energy required for a phase transition is called latent heat.
Energy becomes available to increase the thermal energy (temperature) only after enough hydrogen bonds are broken that the ice can be considered liquid water. The amount of energy consumed in breaking hydrogen bonds in the transition from ice to water is known as the heat of fusion. [12] [8]
It was collected for the first time by James Dewar in 1899 and published with the title "Sur la solidification de l'hydrogène" (English: On the freezing of hydrogen) in the Annales de Chimie et de Physique, 7th series, vol. 18, Oct. 1899. [1] [2] Solid hydrogen has a density of 0.086 g/cm 3 making it one of the lowest-density solids.