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Ethyl acrylate reacts with amines catalyzed by Lewis acids in a Michael addition to β-alanine derivatives in high yields: [13]. The nucleophilic addition at ethyl acrylate as an α,β-unsaturated carbonyl compound is a frequent strategy in the synthesis of pharmaceutical intermediates.
When ethyl acrylate is used as a reactant, ethanol is formed; this forms with the ethyl acrylate an azeotrope of the composition ethanol/ethyl acrylate 72.7:26.3%, which boils at 77.5 °C under atmospheric pressure. [8] To achieve a high reaction yield, the ethanol is distilled off from the reaction mixture.
Methacrylates ( CH 2 =C(CH 3)CO 2 R) and cyanoacrylates ( CH 2 =C(CN)CO 2 R,) are closely related to acrylates. The feature a methyl and a nitrile in place of the H alpha to the carboxy functional group. They share several properties, being polymerized by radicals and being colorless. [2] Structures of some important modified acrylates
2-EHA may refer to: 2-Ethylhexanoic acid; 2-Ethylhexyl acrylate This page was last edited on 4 November 2023 ...
Ethyl acrylate was once used as synthetic food flavoring and was withdrawn by FDA possibly due to cancerogenic effects observed in lab animals. [13] Animal studies showed that high-doses of acrylic acid decreased weight gain. Acrylic acid can be converted to non-toxic lactic acid. [14] Acrylic acid is a constituent of tobacco smoke. [15]
Poly(ethyl acrylate) (PEA) is a family of organic polymers with the formula (CH 2 CHCO 2 CH 2 CH 3) n. It is a synthetic acrylate polymer derived from ethyl acrylate monomer. The polymers are colorless. This homopolymer is far less important than copolymers derived from ethyl acrylate and other monomers.
In the US, due to its potential to irritate the skin, the U.S. Food and Drug Administration (FDA) did not approve its use as a medical adhesive until 1998 with Dermabond (2-octyl cyanoacrylate). [8] A 1986 independent study suggests that cyanoacrylate can be safer and more functional for wound closure than traditional suturing (stitches). [9]
Acrylic resin is a common ingredient in latex paint (UK: "emulsion paint"). Latex paints with a greater proportion of acrylic resin offer better stain protection, greater water resistance, better adhesion, greater resistance to cracking and blistering, and resistance to alkali cleaners compared to those with vinyl. [2]