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The SI unit of molar absorption coefficient is the square metre per mole (m 2 /mol), but in practice, quantities are usually expressed in terms of M −1 ⋅cm −1 or L⋅mol −1 ⋅cm −1 (the latter two units are both equal to 0.1 m 2 /mol). In older literature, the cm 2 /mol is sometimes used; 1 M −1 ⋅cm −1 equals 1000 cm 2 /mol.
The kilogram is defined by setting the Planck constant h exactly to 6.626 070 15 × 10 −34 J⋅s (J = kg⋅m 2 ⋅s −2), given the definitions of the metre and the second. [1] kg: SI: Physics: Basic: ampere: A: I: electric current: The flow of exactly 1 / 1.602 176 634 × 10 −19 times the elementary charge e per second.
Unit Dimension Notes Name Symbol [nb 1] Name Symbol photon energy: n: 1: count of photons n with energy Q p = h c/λ. [nb 2] photon flux: Φ q: count per second: s −1: T −1: photons per unit time, dn/dt with n = photon number. also called photon power: photon intensity: I: count per steradian per second sr −1 ⋅s −1: T −1: dn/dω ...
"The kelvin, symbol K, is the SI unit of thermodynamic temperature. It is defined by taking the fixed numerical value of the Boltzmann constant k to be 1.380 649 × 10 −23 when expressed in the unit J K −1, which is equal to kg m 2 s −2 K −1, where the kilogram, metre and second are defined in terms of h, c and ∆ν Cs." [1]
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
A set of base units in the atomic system as in one proposal are the electron rest mass, the magnitude of the electronic charge, the Planck constant, and the permittivity. [6] [9] In the atomic units system, each of these takes the value 1; the corresponding values in the International System of Units [10]: 132 are given in the table.
The standard state of a material (pure substance, mixture or solution) is a reference point used to calculate its properties under different conditions.A degree sign (°) or a superscript Plimsoll symbol (⦵) is used to designate a thermodynamic quantity in the standard state, such as change in enthalpy (ΔH°), change in entropy (ΔS°), or change in Gibbs free energy (ΔG°).
In atomic physics, Rydberg unit of energy, symbol Ry, corresponds to the energy of the photon whose wavenumber is the Rydberg constant, i.e. the ionization energy of the hydrogen atom in a simplified Bohr model.