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The transfer of electrons from a donor molecule to an acceptor molecule can be spatially separated into a series of intermediate redox reactions. This is an electron transport chain (ETC). Electron transport chains often produce energy in the form of a transmembrane electrochemical potential gradient.
This process of reducing quinone is comparable to that which takes place in the bacterial reaction center. Photosystem II obtains electrons by oxidizing water in a process called photolysis. Molecular oxygen is a byproduct of this process, and it is this reaction that supplies the atmosphere with oxygen.
The electrons are transferred to plastoquinone and two protons, generating plastoquinol, which released into the membrane as a mobile electron carrier. This is the second core process in photosynthesis. The initial stages occur within picoseconds, with an efficiency of 100%. The seemingly impossible efficiency is due to the precise positioning ...
The excited electrons lost from the reaction center of photosystem I are replaced by transfer from plastocyanin, whose electrons come from electron transport through photosystem II. Photosystem II, as the first step of the Z-scheme , requires an external source of electrons to reduce its oxidized chlorophyll a reaction center.
Photosystem I [1] is an integral membrane protein complex that uses light energy to catalyze the transfer of electrons across the thylakoid membrane from plastocyanin to ferredoxin. Ultimately, the electrons that are transferred by Photosystem I are used to produce the moderate-energy hydrogen carrier NADPH. [2]
Electron transfer (ET) occurs when an electron relocates from an atom, ion, or molecule, to another such chemical entity. ET describes the mechanism by which electrons are transferred in redox reactions. [2] Electrochemical processes are ET reactions. ET reactions are relevant to photosynthesis and respiration and commonly involve transition ...
Light-dependent reactions of photosynthesis at the thylakoid membrane. Photosystems are functional and structural units of protein complexes involved in photosynthesis. Together they carry out the primary photochemistry of photosynthesis: the absorption of light and the transfer of energy and electrons.
Another process in photosynthesis that has almost 100% efficiency is charge transfer, again suggesting that quantum mechanical phenomena are at play. [73] In 1966, a study on the photosynthetic bacterium Chromatium found that at temperatures below 100 K, cytochrome oxidation is temperature-independent, slow (on the order of milliseconds), and ...