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  2. Tetrakis (3,5-bis (trifluoromethyl)phenyl)borate - Wikipedia

    en.wikipedia.org/wiki/Tetrakis(3,5-bis(trifluoro...

    The [BAr F 4] − anion with four fluorinated aryl groups distributed tetrahedrally about a central boron atom. Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate is an anion with chemical formula [{3,5-(CF 3) 2 C 6 H 3} 4 B] −, which is commonly abbreviated as [BAr F 4] −, indicating the presence of fluorinated aryl (Ar F) groups.

  3. Hydroboration–oxidation reaction - Wikipedia

    en.wikipedia.org/wiki/Hydroboration–oxidation...

    The boron reagent is converted to boric acid. The reaction was originally described by H.C. Brown in 1957 for the conversion of 1-hexene into 1-hexanol. [3] Hexanol synthesis. Knowing that the group containing the boron will be replaced by a hydroxyl group, it can be seen that the initial hydroboration step determines the regioselectivity.

  4. Hydroboration - Wikipedia

    en.wikipedia.org/wiki/Hydroboration

    This chemical reaction is useful in the organic synthesis of organic compounds. [1] Hydroboration produces organoborane compounds that react with a variety of reagents to produce useful compounds, such as alcohols, amines, or alkyl halides. The most widely known reaction of the organoboranes is oxidation to produce alcohols from alkenes.

  5. Organoboron chemistry - Wikipedia

    en.wikipedia.org/wiki/Organoboron_chemistry

    Boron is renowned for cluster species, e.g. dodecaborate [B 12 H 12] 2-. Such clusters have many organic derivatives. One example is [B 12 (CH 3) 12] 2-and its radical derivative [B 12 (CH 3) 12] −. [16] Related cluster compounds with carbon vertices are carboranes; the best known is orthocarborane, C 2 B 10 H 12. Carboranes have few ...

  6. Boranes - Wikipedia

    en.wikipedia.org/wiki/Boranes

    In the US, a team led by Schlesinger developed the basic chemistry of the anionic boron hydrides and the related aluminium hydrides. Schlesinger's work laid the foundation for a host of boron hydride reagents for organic synthesis, most of which were developed by his student Herbert C. Brown. Borane-based reagents are now widely used in organic ...

  7. Diisopinocampheylborane - Wikipedia

    en.wikipedia.org/wiki/Diisopinocampheylborane

    Diisopinocampheylborane is an organoborane that is useful for asymmetric synthesis. This colourless solid is the precursor to a range of related reagents. The compound was reported in 1961 by Zweifel and Brown in a pioneering demonstration of asymmetric synthesis using boranes. The reagent is mainly used for the synthesis of chiral secondary ...

  8. BODIPY - Wikipedia

    en.wikipedia.org/wiki/BODIPY

    2, whose molecule consists of a boron difluoride group BF 2 joined to a dipyrromethene group C 9 H 7 N 2; specifically, the compound 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene in the IUPAC nomenclature. [1] The common name is an abbreviation for "boron-dipyrromethene". It is a red crystalline solid, stable at ambient temperature, soluble in ...

  9. Borylation - Wikipedia

    en.wikipedia.org/wiki/Borylation

    Around 12 years later, Dr. Chattopadhyay and his team from Centre of Biomedical Research, U.P, India discovered an elegant technology for the meta-selective C–H bond activation and borylation. The team had shown that using the same substrate, one can switch the other positional selectivity just changing the ligand.