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  2. Hydroboration–oxidation reaction - Wikipedia

    en.wikipedia.org/wiki/Hydroboration–oxidation...

    The boron reagent is converted to boric acid. The reaction was originally described by H.C. Brown in 1957 for the conversion of 1-hexene into 1-hexanol. [3] Hexanol synthesis. Knowing that the group containing the boron will be replaced by a hydroxyl group, it can be seen that the initial hydroboration step determines the regioselectivity.

  3. Hydroboration - Wikipedia

    en.wikipedia.org/wiki/Hydroboration

    This chemical reaction is useful in the organic synthesis of organic compounds. [1] Hydroboration produces organoborane compounds that react with a variety of reagents to produce useful compounds, such as alcohols, amines, or alkyl halides. The most widely known reaction of the organoboranes is oxidation to produce alcohols from alkenes.

  4. Organoboron chemistry - Wikipedia

    en.wikipedia.org/wiki/Organoboron_chemistry

    Boron-boron multiple bonds are rare, although doubly-bonded dianions have been known since the 1990s. [20] Neutral analogues use NHC adducts, such as the following diborane(2) derivative: [21] [22] Each boron atom has an attached proton and is coordinated to a NHC carbene. [23] [24] A reported diboryne is based on similar chemistry. [25]

  5. Tetrakis (3,5-bis (trifluoromethyl)phenyl)borate - Wikipedia

    en.wikipedia.org/wiki/Tetrakis(3,5-bis(trifluoro...

    The [BAr F 4] − anion with four fluorinated aryl groups distributed tetrahedrally about a central boron atom. Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate is an anion with chemical formula [{3,5-(CF 3) 2 C 6 H 3} 4 B] −, which is commonly abbreviated as [BAr F 4] −, indicating the presence of fluorinated aryl (Ar F) groups.

  6. Boron trichloride - Wikipedia

    en.wikipedia.org/wiki/Boron_trichloride

    One consequence of this synthesis route is that samples of boron trichloride are often contaminated with phosgene. [3] In the laboratory BCl 3 can be prepared by treating with AlCl 3 with BF 3, a halide exchange reaction. [4] BCl 3 is a trigonal planar molecule like the other boron trihalides. The B-Cl bond length is 175 pm.

  7. Borane–tetrahydrofuran - Wikipedia

    en.wikipedia.org/wiki/Borane–tetrahydrofuran

    The following organoboron reagents are prepared from borane-THF: 9-borabicyclo[3.3.1]nonane, Alpine borane, diisopinocampheylborane. It is also used as a source of borane (BH 3 ) for the formation of adducts.

  8. Borylation - Wikipedia

    en.wikipedia.org/wiki/Borylation

    Organoboron compounds are organic compounds containing a carbon-boron bond. Organoboron compounds have broad applications for chemical synthesis because the C–B bond can easily be converted into a C–X (X = Br, Cl), C–O, C–N, or C–C bond.

  9. Borate esters - Wikipedia

    en.wikipedia.org/wiki/Borate_esters

    This procedure is used for analysis of trace amounts of borate and for analysis of boron in steel. [2] Like all boron compounds, alkyl borates burn with a characteristic green flame. This property is used to determine the presence of boron in qualitative analysis. [3] Trimethyl borate is a popular borate ester used in organic synthesis.