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  2. Van 't Hoff equation - Wikipedia

    en.wikipedia.org/wiki/Van_'t_Hoff_equation

    For a reversible reaction, the equilibrium constant can be measured at a variety of temperatures. This data can be plotted on a graph with ln K eq on the y-axis and ⁠ 1 / T ⁠ on the x axis. The data should have a linear relationship, the equation for which can be found by fitting the data using the linear form of the Van 't Hoff equation

  3. Determination of equilibrium constants - Wikipedia

    en.wikipedia.org/wiki/Determination_of...

    The value of the equilibrium constant for the formation of a 1:1 complex, such as a host-guest species, may be calculated with a dedicated spreadsheet application, Bindfit: [4] In this case step 2 can be performed with a non-iterative procedure and the pre-programmed routine Solver can be used for step 3.

  4. Thermodynamic versus kinetic reaction control - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_versus...

    Under pure thermodynamic reaction control, when the equilibrium has been reached, the product distribution will be a function of the stabilities G°. After an infinite amount of reaction time, the ratio of product concentrations will equal the equilibrium constant K eq and therefore be a function of the difference in Gibbs free energies,

  5. Equilibrium constant - Wikipedia

    en.wikipedia.org/wiki/Equilibrium_constant

    The equilibrium constant of a chemical reaction is the value of its reaction quotient at chemical equilibrium, a state approached by a dynamic chemical system after sufficient time has elapsed at which its composition has no measurable tendency towards further change.

  6. Reaction quotient - Wikipedia

    en.wikipedia.org/wiki/Reaction_quotient

    The reaction quotient plays a crucial role in understanding the direction and extent of a chemical reaction's progress towards equilibrium: Equilibrium condition: At equilibrium, the reaction quotient (Q) is equal to the equilibrium constant (K) for the reaction. This condition is represented as Q = K, indicating that the forward and reverse ...

  7. Free-energy relationship - Wikipedia

    en.wikipedia.org/wiki/Free-energy_relationship

    The Hammett equation predicts the equilibrium constant or reaction rate of a reaction from a substituent constant and a reaction type constant. The Edwards equation relates the nucleophilic power to polarisability and basicity. The Marcus equation is an example of a quadratic free-energy relationship (QFER). [citation needed]

  8. Hammett equation - Wikipedia

    en.wikipedia.org/wiki/Hammett_equation

    A plot of log(k) against log(K A) showed a linear relationship. Such linear relationships correspond to linear free energy relationships, which strongly imply that the effect of the substituents are exerted through changes of potential energy and that the steric and entropy terms remain almost constant through the series. The linear ...

  9. Rate-determining step - Wikipedia

    en.wikipedia.org/wiki/Rate-determining_step

    As an example, consider the gas-phase reaction NO 2 + CO → NO + CO 2.If this reaction occurred in a single step, its reaction rate (r) would be proportional to the rate of collisions between NO 2 and CO molecules: r = k[NO 2][CO], where k is the reaction rate constant, and square brackets indicate a molar concentration.

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