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Hydrazines (R 2 N−NR 2) are a class of chemical compounds with two nitrogen atoms linked via a covalent bond and which carry from one up to four alkyl or aryl substituents. Hydrazines can be considered as derivatives of the inorganic hydrazine (H 2 N−NH 2), in which one or more hydrogen atoms have been replaced by hydrocarbon groups. [1]
Hydrazine is an inorganic compound with the chemical formula N 2 H 4.It is a simple pnictogen hydride, and is a colourless flammable liquid with an ammonia-like odour.Hydrazine is highly hazardous unless handled in solution as, for example, hydrazine hydrate (N 2 H 4 ·xH 2 O).
Heliotropism, a form of tropism, is the diurnal or seasonal motion of plant parts (flowers or leaves) in response to the direction of the Sun. The habit of some plants to move in the direction of the Sun, a form of tropism, was already known by the Ancient Greeks. They named one of those plants after that property Heliotropium, meaning "sun turn".
When derived from hydrazine itself, hydrazones condense with a second equivalent of a carbonyl to give azines: [11] R 2 C=N−NH 2 + R 2 C=O → R 2 C=N−N=CR 2 + H 2 O. Hydrazones are intermediates in the Wolff–Kishner reduction. Hydrazones are reactants in hydrazone iodination, the Shapiro reaction, and the Bamford–Stevens reaction to ...
The Olin Raschig process is a chemical process for the production of hydrazine.The main steps in this process, patented by German chemist Friedrich Raschig in 1906 and one of three reactions named after him, are the formation of monochloramine from ammonia and hypochlorite, and the subsequent reaction of monochloramine with ammonia towards hydrazine. [1]
The generic formula of an azine. For an aldazine, R 2 = H.. Azines are a functional class of organic compounds with the connectivity RR'C=N-N=CRR'. These compounds are the product of the condensation of hydrazine with ketones and aldehydes, although in practice they are often made by alternative routes.
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Many millions of kilograms of hydrazine are produced annually by this method that involves a step wherein ammonia is oxidized in the presence of methyl ethyl ketone to give the oxaziridine: [20] Me(Et)C=O + NH 3 + H 2 O 2 → Me(Et)CONH + H 2 O. In subsequent steps the oxaziridine is converted to the hydrazone, which is the immediate in the way ...