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The aminoxyl radical (N-O•) combines with free radicals in polymers: N-O• + R• → N-O-R Although they are traditionally considered as light stabilizers, they can also stabilize thermal degradation. Even though HALS are extremely effective in polyolefins, polyethylene and polyurethane, they are ineffective in polyvinyl chloride (PVC). It ...
Polymers become charged through the dissociation of the monomer side groups. If more monomer side groups are dissociated, the polymer has a higher charge. In turn, the charge of the polymer classifies the polyelectrolyte, which can be positive (cationic) or negative (anionic).
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In polymer chemistry, emulsion polymerization is a type of radical polymerization that usually starts with an emulsion incorporating water, monomers, and surfactants.The most common type of emulsion polymerization is an oil-in-water emulsion, in which droplets of monomer (the oil) are emulsified (with surfactants) in a continuous phase of water.
Crystal structure of β-glucosidase from Thermotoga neapolitana (PDB: 5IDI).Thermostable protein, active at 80°C and with unfolding temperature of 101°C. [1]In materials science and molecular biology, thermostability is the ability of a substance to resist irreversible change in its chemical or physical structure, often by resisting decomposition or polymerization, at a high relative ...
Specific materials and their applications include polymer-protein and polymer-drug conjugates, mediation of enzyme activity, molecular recognition processes and polymeric micelles which can deliver a drug to a specific site in the body. [19] RAFT has also been used to graft polymer chains onto polymeric surfaces, for example, polymeric ...
The onset of thermal degradation dictates the maximum temperature at which a polymer can be used. It is an important limitation in how the polymer is manufactured and processed. For instance, polymers become less viscous at higher temperatures which makes injection moulding easier and faster, but thermal degradation places a ceiling temperature ...
In industrial chemistry, a stabilizer or stabiliser is a chemical that is used to prevent degradation. [1] Above all, heat and light stabilizers are added to plastic and rubber materials because they ensure safe processing and protect products against aging and weathering.
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