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The aminoxyl radical (N-O•) combines with free radicals in polymers: N-O• + R• → N-O-R Although they are traditionally considered as light stabilizers, they can also stabilize thermal degradation. Even though HALS are extremely effective in polyolefins, polyethylene and polyurethane, they are ineffective in polyvinyl chloride (PVC). It ...
Hindered amine light stabilizers (HALS) are chemical compounds containing an amine functional group that are used as stabilizers in plastics and polymers. [1] These compounds are typically derivatives of tetramethylpiperidine and are primarily used to protect the polymers from the effects of photo-oxidation; as opposed to other forms of polymer degradation such as ozonolysis.
Polymers become charged through the dissociation of the monomer side groups. If more monomer side groups are dissociated, the polymer has a higher charge. In turn, the charge of the polymer classifies the polyelectrolyte, which can be positive (cationic) or negative (anionic).
Polymerization in which polymer is formed in monomer, or monomer-solvent droplets in a continuous phase that is a nonsolvent for both the monomer and the formed polymer. Note 1: In suspension polymerization, the initiator is located mainly in the monomer phase. Note 2: Monomer or monomer-solvent droplets in suspension polymerization have
In polymer science, dispersion polymerization is a heterogeneous polymerization process carried out in the presence of a polymeric stabilizer in the reaction medium. . Dispersion polymerization is a type of precipitation polymerization, meaning the solvent selected as the reaction medium is a good solvent for the monomer and the initiator, but is a non-solvent for the po
Specific materials and their applications include polymer-protein and polymer-drug conjugates, mediation of enzyme activity, molecular recognition processes and polymeric micelles which can deliver a drug to a specific site in the body. [19] RAFT has also been used to graft polymer chains onto polymeric surfaces, for example, polymeric ...
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It is widely used in place of polystyrene owing to its greater thermal resistance. The chains of between 70 and 80% by weight styrene and 20 to 30% acrylonitrile. [ 1 ] Larger acrylonitrile content improves mechanical properties and chemical resistance, but also adds a yellow tint to the normally transparent plastic.