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In case of atactic polypropylene, the methyl group (-CH 3) is randomly aligned, alternating (alternating) for syndiotactic polypropylene and evenly for isotactic polypropylene. This has an impact on the crystallinity (amorphous or semi-crystalline) and the thermal properties (expressed as glass transition point T g and melting point T m ).
Many plastics are completely amorphous (without a highly ordered molecular structure), [23] including thermosets, polystyrene, and methyl methacrylate (PMMA). Crystalline plastics exhibit a pattern of more regularly spaced atoms, such as high-density polyethylene (HDPE), polybutylene terephthalate (PBT), and polyether ether ketone (PEEK ...
Polymer morphology is a microscale property that is largely dictated by the amorphous or crystalline portions of the polymer chains and their influence on each other. Microscopy techniques are especially useful in determining these microscale properties, as the domains created by the polymer morphology are large enough to be viewed using modern ...
The PP and PE components of a blend constitute the "crystalline phase", and the rubber and branched PE chains and PE/PP end groups gives the "amorphous phase". If PP and PE are the dominant component of a TPO blend then the rubber fraction will be dispersed into a continuous matrix of "crystalline" polypropylene.
For example, atactic polypropylene is usually amorphous and transparent while syndiotactic polypropylene, which has crystallinity ~50%, is opaque. [30] Crystallinity also affects dyeing of polymers: crystalline polymers are more difficult to stain than amorphous ones because the dye molecules penetrate through amorphous regions with greater ease.
Prince William and Kate Middleton joined the rest of the royal family for their annual Christmas walk in Sandringham on Christmas day, and were accompanied by Prince William's step siblings, Laura ...
Therefore, the polypropylene product generally did not require additional purification steps to remove the atactic or low crystalline fraction. This meant that the APP supply from polypropylene plants using standard first- and early second-generation Z-N catalysts decreased as commercial plants adopted the new catalysts.
A type of bacteria dubbed “Conan the Bacterium” can withstand radiation thousands of times stronger than what can kill a human. Now, scientists have figured out why.