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Terpenes are classified by the number of carbons: monoterpenes (C 10), sesquiterpenes (C 15), diterpenes (C 20), as examples. The terpene alpha-pinene is a major component of the common solvent, turpentine. The one terpene that has major applications is natural rubber (i.e., polyisoprene).
Monoterpenes are a class of terpenes that consist of two isoprene units and have the molecular formula C 10 H 16. Monoterpenes may be linear (acyclic) or contain rings (monocyclic and bicyclic). Modified terpenes, such as those containing oxygen functionality or missing a methyl group, are called monoterpenoids. Monoterpenes and monoterpenoids ...
Terpenoids are modified terpenes, [7] wherein methyl groups have been moved or removed, or oxygen atoms added. Some authors use the term "terpene" more broadly, to include the terpenoids. Just like terpenes, the terpenoids can be classified according to the number of isoprene units that comprise the parent terpene:
Although a wide range of terpene structures exist, few of them are biologically significant; by contrast, diterpenoids possess a rich pharmacology and include important compounds such as retinol, phytol or taxadiene.
Sesquiterpenes are a class of terpenes that consist of three isoprene units and often have the molecular formula C 15 H 24. Like monoterpenes, sesquiterpenes may be cyclic or contain rings, including many combinations. Biochemical modifications such as oxidation or rearrangement produce the related sesquiterpenoids. [1]
The vast heterogeneity of structures underlying this class of compounds makes generalizations difficult; they're a subclass of terpenoids, oxygenated derivatives of terpene hydrocarbons. Terpenes in turn are formally made up of five-carbon isoprene units (The alternate steroid base is a terpene missing a few carbon atoms). Derivatives are ...
As a term, phytochemicals is generally used to describe plant compounds that are under research with unestablished effects on health, and are not essential nutrients. Regulatory agencies governing food labeling in Europe and the United States have provided guidance for industry to limit or prevent health claims about phytochemicals on food ...
In this pathway, bioactive GA is produced from trans-geranylgeranyl diphosphate (GGDP), with the participation of three classes of enzymes: terpene syntheses (TPSs), cytochrome P450 monooxygenases (P450s), and 2-oxoglutarate–dependent dioxygenases (2ODDs). [11] [8] The MEP pathway follows eight steps: [8]
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