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The multiple valued version of log(z) is a set, but it is easier to write it without braces and using it in formulas follows obvious rules. log(z) is the set of complex numbers v which satisfy e v = z; arg(z) is the set of possible values of the arg function applied to z. When k is any integer:
The measurement of pH can become difficult at extremely acidic or alkaline conditions, such as below pH 2.5 (ca. 0.003 mol/dm 3 acid) or above pH 10.5 (above ca. 0.0003 mol/dm 3 alkaline). This is due to the breakdown of the Nernst equation in such conditions when using a glass electrode.
log 10 β values between about 2 and 11 can be measured directly by potentiometric titration using a glass electrode. This enormous range of stability constant values (ca. 100 to 10 11) is possible because of the logarithmic response of the electrode. The limitations arise because the Nernst equation breaks down at very low or very high pH.
The logarithm keys (LOG for base 10 and LN for base e) on a TI-83 Plus graphing calculator. Logarithms are easy to compute in some cases, such as log 10 (1000) = 3. In general, logarithms can be calculated using power series or the arithmetic–geometric mean, or be retrieved from a precalculated logarithm table that provides a fixed precision.
An important property of base-10 logarithms, which makes them so useful in calculations, is that the logarithm of numbers greater than 1 that differ by a factor of a power of 10 all have the same fractional part. The fractional part is known as the mantissa. [b] Thus, log tables need only show the fractional part. Tables of common logarithms ...
Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
An LNS can be considered as a floating-point number with the significand being always equal to 1 and a non-integer exponent. This formulation simplifies the operations of multiplication, division, powers and roots, since they are reduced down to addition, subtraction, multiplication, and division, respectively.
The Henderson–Hasselbalch equation can be used to model these equilibria. It is important to maintain this pH of 7.4 to ensure enzymes are able to work optimally. [10] Life threatening Acidosis (a low blood pH resulting in nausea, headaches, and even coma, and convulsions) is due to a lack of functioning of enzymes at a low pH. [10]