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The Kelvin equation describes the change in vapour pressure due to a curved liquid–vapor interface, such as the surface of a droplet. The vapor pressure at a convex curved surface is higher than that at a flat surface. The Kelvin equation is dependent upon thermodynamic principles and does not allude to special properties of materials.
In fluid dynamics, the pressure coefficient is a dimensionless number which describes the relative pressures throughout a flow field. The pressure coefficient is used in aerodynamics and hydrodynamics. Every point in a fluid flow field has its own unique pressure coefficient, C p.
Darcy's law is an equation that describes the flow of a fluid through a porous medium and through a Hele-Shaw cell.The law was formulated by Henry Darcy based on results of experiments [1] on the flow of water through beds of sand, forming the basis of hydrogeology, a branch of earth sciences.
Δp is the pressure difference between the two ends, L is the length of pipe, μ is the dynamic viscosity, Q is the volumetric flow rate, R is the pipe radius, A is the cross-sectional area of pipe. The equation does not hold close to the pipe entrance. [8]: 3 The equation fails in the limit of low viscosity, wide and/or short pipe.
The Clausius–Clapeyron relation, in chemical thermodynamics, specifies the temperature dependence of pressure, most importantly vapor pressure, at a discontinuous phase transition between two phases of matter of a single constituent. It is named after Rudolf Clausius [1] and Benoît Paul Émile Clapeyron. [2]
If the pressure is increased by the addition of an inert gas, then neither the composition at equilibrium nor the equilibrium constant are appreciably affected (because the partial pressures remain constant, assuming an ideal-gas behaviour of all gases involved). However, the composition at equilibrium will depend appreciably on pressure when:
As an example for pipe flows, with the Reynolds number based on the pipe diameter: =. Here l is the turbulence or eddy length scale, given below, and c μ is a k – ε model parameter whose value is typically given as 0.09;
The mathematical similarities between the expressions for shear viscocity, thermal conductivity and diffusion coefficient of the ideal (dilute) gas is not a coincidence; It is a direct result of the Onsager reciprocal relations (i.e. the detailed balance of the reversible dynamics of the particles), when applied to the convection (matter flow ...