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Hydrofluorocarbons (HFCs) are synthetic organic compounds that contain fluorine and hydrogen atoms, and are the most common type of organofluorine compounds. Most are gases at room temperature and pressure.
Elemental fluorine and virtually all fluorine compounds are produced from hydrogen fluoride or its aqueous solution, hydrofluoric acid. Hydrogen fluoride is produced in kilns by the endothermic reaction of fluorite (CaF 2) with sulfuric acid: [169] CaF 2 + H 2 SO 4 → 2 HF(g) + CaSO 4. The gaseous HF can then be absorbed in water or liquefied ...
The covalent radius of fluorine of about 71 picometers found in F 2 molecules is significantly larger than that in other compounds because of this weak bonding between the two fluorine atoms. [9] This is a result of the relatively large electron and internuclear repulsions, combined with a relatively small overlap of bonding orbitals arising ...
Hydrogen fluoride is typically produced by the reaction between sulfuric acid and pure grades of the mineral fluorite: [14] CaF 2 + H 2 SO 4 → 2 HF + CaSO 4 About 20% of manufactured HF is a byproduct of fertilizer production, which generates hexafluorosilicic acid .
Hydrofluorocarbons (HFCs), organic compounds that contain fluorine and hydrogen atoms, are the most common type of organofluorine compounds. They are commonly used in air conditioning and as refrigerants [5] in place of the older chlorofluorocarbons such as R-12 and hydrochlorofluorocarbons such as R-21.
Perfluoroalkanes are very stable because of the strength of the carbon–fluorine bond, one of the strongest in organic chemistry. [4] Its strength is a result of the electronegativity of fluorine imparting partial ionic character through partial charges on the carbon and fluorine atoms, which shorten and strengthen the bond (compared to carbon-hydrogen bonds) through favorable covalent ...
Organofluorine compounds are pervasive. Many drugs, many polymers, refrigerants, and many inorganic compounds are made from fluoride-containing reagents. Often fluorides are converted to hydrogen fluoride, which is a major reagent and precursor to reagents. Hydrofluoric acid and its anhydrous form, hydrogen fluoride, are particularly important. [4]
Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water.Solutions of HF are colorless, acidic and highly corrosive.A common concentration is 49% (48-52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling point near room temperature.