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The Birch reduction is an organic reaction that is used to convert arenes to 1,4-cyclohexadienes.The reaction is named after the Australian chemist Arthur Birch and involves the organic reduction of aromatic rings in an amine solvent (traditionally liquid ammonia) with an alkali metal (traditionally sodium) and a proton source (traditionally an alcohol).
Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH 3 (aq). Although the name ammonium hydroxide suggests a salt with the composition [NH + 4][OH −
Magnesium has a mild reaction with cold water. The reaction is short-lived because the magnesium hydroxide layer formed on the magnesium is almost insoluble in water and prevents further reaction. Mg(s) + 2H 2 O(l) Mg(OH) 2 (s) + H 2 (g) [11] A metal reacting with cold water will produce a metal hydroxide and hydrogen gas.
Another common example is the reaction of a primary amine or secondary amine with a carboxylic acid or with a carboxylic acid derivative to form an amide. This reaction is widely used, especially in the synthesis of peptides. On the simple addition of an amine to a carboxylic acid, a salt of the organic acid and base is obtained.
The protonated isocyanate is attacked by water forming carbamate 4, which after deprotonation loses carbon dioxide to the amine. Reaction mechanism for the amine formation from a carboxylic acid via Schmidt reaction. In the reaction mechanism for the Schmidt reaction of ketones, the carbonyl group is activated by protonation for nucleophilic ...
However, trapping with water, to form the acid is the most common form. General homologation reaction, Arndt-Eistert has R 2 = H, RXH=H 2 O. In the most basic form, where R 2 = H, RXH=H 2 O, the reaction lengthens the alkyl chain of a carboxylic acid by a methylene. However, there is great synthetic utility in the variety of reactions one can ...
The classic example of a dehydration reaction is the Fischer esterification, which involves treating a carboxylic acid with an alcohol to give an ester RCO 2 H + R′OH ⇌ RCO 2 R′ + H 2 O. Often such reactions require the presence of a dehydrating agent, i.e. a substance that reacts with water.
Magnesium perchlorate is a white powder that is easily soluble in water, which can be obtained by the reaction of magnesium oxide and perchloric acid. The hexahydrate crystallizes from the solution, and then it is dried with phosphorus pentoxide in a vacuum at 200~250 °C to obtain the anhydrous form.