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When metallic iron (oxidation state 0) is placed in a solution of hydrochloric acid, iron(II) chloride is formed, with release of hydrogen gas, by the reaction Fe 0 + 2 H + → Fe 2+ + H 2. Iron(II) is oxidized by hydrogen peroxide to iron(III), forming a hydroxyl radical and a hydroxide ion in the process. This is the Fenton reaction.
Direct reduction processes can be divided roughly into two categories: gas-based and coal-based. In both cases, the objective of the process is to remove the oxygen contained in various forms of iron ore (sized ore, concentrates, pellets, mill scale, furnace dust, etc.) in order to convert the ore to metallic iron, without melting it (below 1,200 °C (2,190 °F)).
Low-pressure phase diagram of pure iron. BCC is body centered cubic and FCC is face-centered cubic. Iron-carbon eutectic phase diagram, showing various forms of Fe x C y substances. Iron allotropes, showing the differences in structure. The alpha iron (α-Fe) is a body-centered cubic (BCC) and the gamma iron (γ-Fe) is a face-centered cubic (FCC).
Iron is a chemical element; it has the symbol Fe (from Latin ferrum 'iron') and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's outer and inner core.
In the iron and steel industry, direct reduction is a set of processes for obtaining iron from iron ore, by reducing iron oxides without melting the metal. The resulting product is pre-reduced iron ore. Historically, direct reduction was used to obtain a mix of iron and slag called a bloom in a bloomery.
Nitrate reduction by iron powder is observed at pH ≤ 4. [11] Ammonia is the end product. Using nanoscale iron, Nitrogen gas (N 2) is the product. [12] Nitrated aromatics are reduced by bulk iron. [7] [13] [14] Chlorinated pesticides such as DDT, DDD, and DDE. The rates of dechlorination are enhanced by the surfactant Triton X-114. [15]
The iron compounds produced on the largest scale in industry are iron(II) sulfate (FeSO 4 ·7H 2 O) and iron(III) chloride (FeCl 3). The former is one of the most readily available sources of iron(II), but is less stable to aerial oxidation than Mohr's salt ((NH 4) 2 Fe(SO 4) 2 ·6H 2 O). Iron(II) compounds tend to be oxidized to iron(III ...
Examples include iron, nickel, lead and zinc. Copper is also considered a base metal because it oxidizes relatively easily, although it does not react with HCl. In mining and economics, the term base metals refers to industrial non-ferrous metals excluding precious metals. These include copper, lead, nickel and zinc. [3]