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Different side chains characterize each type of chlorophyll molecule, and alters the absorption spectrum of light. [ 10 ] [ 11 ] For instance, the only difference between chlorophyll a and chlorophyll b is that chlorophyll b has an aldehyde instead of a methyl group at the C-7 position.
[21] [22] [23] In this way, the concentration of chlorophyll within a leaf can be estimated. [24] Methods also exist to separate chlorophyll a and chlorophyll b. In diethyl ether, chlorophyll a has approximate absorbance maxima of 430 nm and 662 nm, while chlorophyll b has approximate maxima of 453 nm and 642 nm. [25]
BChl roughly resembles the chlorophyll molecule found in green plants, but, due to minor structural differences, its peak absorption wavelength is shifted into the infrared, with wavelengths as long as 1000 nm. Bph has the same structure as BChl, but the central magnesium ion is replaced by two protons.
The antenna pigments are predominantly chlorophyll b, xanthophylls, and carotenes. Chlorophyll a is known as the core pigment. Their absorption spectra are non-overlapping and broaden the range of light that can be absorbed in photosynthesis. The carotenoids have another role as an antioxidant to prevent photo-oxidative damage of chlorophyll ...
Mg 2+ is the coordinating metal ion in the chlorophyll molecule, and in plants where the ion is in high supply about 6% of the total Mg 2+ is bound to chlorophyll. [ 4 ] [ 88 ] [ 89 ] Thylakoid stacking is stabilised by Mg 2+ and is important for the efficiency of photosynthesis, allowing phase transitions to occur.
Top: Absorption spectra for chlorophyll-A, chlorophyll-B, and carotenoids extracted in a solution. Bottom: PAR action spectrum (oxygen evolution per incident photon) of an isolated chloroplast. Chlorophyll , the most abundant plant pigment, is most efficient in capturing red and blue light.
P680, or photosystem II primary donor, is the reaction-center chlorophyll a molecular dimer associated with photosystem II in plants, algae, and cyanobacteria, and central to oxygenic photosynthesis. Etymology
The following is a breakdown of the energetics of the photosynthesis process from Photosynthesis by Hall and Rao: [6]. Starting with the solar spectrum falling on a leaf, 47% lost due to photons outside the 400–700 nm active range (chlorophyll uses photons between 400 and 700 nm, extracting the energy of one 700 nm photon from each one)