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Soil texture and structure strongly affect soil porosity and gas diffusion. It is the total pore space of soil, not the pore size, and the degree of pore interconnection (or conversely pore sealing), together with water content, air turbulence and temperature, that determine the rate of diffusion of gases into and out of soil.
Soil gases (soil atmosphere [1]) are the gases found in the air space between soil components. The spaces between the solid soil particles, if they do not contain water, are filled with air. The primary soil gases are nitrogen, carbon dioxide and oxygen. [2] Oxygen is critical because it allows for respiration of both plant roots and soil ...
Soil bulk density is equal to the dry mass of the soil divided by the volume of the soil; i.e., it includes air space and organic materials of the soil volume. Thereby soil bulk density is always less than soil particle density and is a good indicator of soil compaction. [ 47 ]
Liquefaction of gases is physical conversion of a gas into a liquid state (condensation). The liquefaction of gases is a complicated process that uses various compressions and expansions to achieve high pressures and very low temperatures, using, for example, turboexpanders .
The pore space of soil contains the liquid and gas phases of soil, i.e., everything but the solid phase that contains mainly minerals of varying sizes as well as organic compounds. In order to understand porosity better a series of equations have been used to express the quantitative interactions between the three phases of soil.
In his 1803 publication about the quantity of gases absorbed by water, [1] William Henry described the results of his experiments: … water takes up, of gas condensed by one, two, or more additional atmospheres, a quantity which, ordinarily compressed, would be equal to twice, thrice, &c. the volume absorbed under the common pressure of the atmosphere.
The absorption of gases in liquids depends on the solubility of the specific gas in the specific liquid, the concentration of gas, customarily measured by partial pressure, and temperature. [1] In the study of decompression theory the behaviour of gases dissolved in the tissues is investigated and modeled for variations of pressure over time. [7]
A vapor can exist in equilibrium with a liquid (or solid), in which case the gas pressure equals the vapor pressure of the liquid (or solid). A supercritical fluid (SCF) is a gas whose temperature and pressure are above the critical temperature and critical pressure respectively. In this state, the distinction between liquid and gas disappears.