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The number of open chain stereoisomers for an aldose monosaccharide is larger by one than that of a ketose monosaccharide of the same length. Every ketose will have 2 (n−3) stereoisomers where n > 2 is the number of carbons. Every aldose will have 2 (n−2) stereoisomers where n > 2 is the number of carbons. These are also referred to as ...
Fischer projection of D-glyceraldehyde. Like most carbohydrates, simple aldoses have the general chemical formula C n (H 2 O) n.Because formaldehyde (n=1) and glycolaldehyde (n=2) are not generally considered to be carbohydrates, [1] the simplest possible aldose is the triose glyceraldehyde, which only contains three carbon atoms.
The monosaccharides can be divided into two groups: the aldoses, which have an aldehyde group, and the ketoses, which have a ketone group. Ketoses must first tautomerize to aldoses before they can act as reducing sugars. The common dietary monosaccharides galactose, glucose and fructose are all reducing sugars.
All monosaccharide ketoses are reducing sugars, because they can tautomerize into aldoses via an enediol intermediate, and the resulting aldehyde group can be oxidised, for example in the Tollens' test or Benedict's test. [3] Ketoses that are bound into glycosides, for example in the case of the fructose moiety of sucrose, are nonreducing ...
In chemistry, a hexose is a monosaccharide (simple sugar) with six carbon atoms. [1] [2] The chemical formula for all hexoses is C 6 H 12 O 6, and their molecular weight is 180.156 g/mol. [3] Hexoses exist in two forms, open-chain or cyclic, that easily convert into each other in aqueous solutions. [4]
The table shows all aldoses with 3 to 6 carbon atoms, and a few ketoses. For chiral molecules, only the ' D-' form (with the next-to-last hydroxyl on the right side) is shown; the corresponding forms have mirror-image structures. Some of these monosaccharides are only synthetically prepared in the laboratory and not found in nature.
In organic chemistry, a sugar acid or acidic sugar is a monosaccharide with a carboxyl group at one end or both ends of its chain. [1] Main classes of sugar acids include: Aldonic acids, in which the aldehyde group (−CH=O) located at the initial end of an aldose is oxidized.
Glyceraldehyde (glyceral) is a triose monosaccharide with chemical formula C 3 H 6 O 3. It is the simplest of all common aldoses. It is a sweet, colorless, crystalline solid that is an intermediate compound in carbohydrate metabolism.